Light-Induced Anion Phase Segregation in Mixed Halide Perovskites
Тип публикации: Journal Article
Дата публикации: 2017-12-22
scimago Q1
wos Q1
БС1
SJR: 6.799
CiteScore: 29.6
Impact factor: 18.2
ISSN: 23808195
Materials Chemistry
Chemistry (miscellaneous)
Energy Engineering and Power Technology
Fuel Technology
Renewable Energy, Sustainability and the Environment
Краткое описание
Hybrid lead halide perovskites such as MAPbI3 (MA = CH3NH3+) and their mixed halide analogues represent an emerging class of materials for solar energy conversion. Intriguing aspects include sizable carrier diffusion lengths, large optical absorption coefficients, and certified power conversion efficiencies that now exceed 22%. Halide-composition-tunable band gaps also make MAPb(I1–xBrx)3 systems ideal candidates for tandem solar cells. Unfortunately, preventing the effective integration of MAPb(I1–xBrx)3 into working devices are intrinsic instabilities due to light-induced halide phase segregation. Namely, under illumination, mixed halide perovskites reversibly segregate into low-band-gap I-rich and high-band-gap Br-rich domains. Under electrical bias, halide migration has also been proposed as the source of undesirable charge injection barriers that degrade photovoltaic performance. In this Perspective, we review the origin of light-induced halide phase segregation, its effects on photovoltaic response,...
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ГОСТ
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Brennan M. C. et al. Light-Induced Anion Phase Segregation in Mixed Halide Perovskites // ACS Energy Letters. 2017. Vol. 3. No. 1. pp. 204-213.
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Brennan M. C., Draguta S., Kamat P. V., Kuno M. Light-Induced Anion Phase Segregation in Mixed Halide Perovskites // ACS Energy Letters. 2017. Vol. 3. No. 1. pp. 204-213.
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TY - JOUR
DO - 10.1021/acsenergylett.7b01151
UR - https://doi.org/10.1021/acsenergylett.7b01151
TI - Light-Induced Anion Phase Segregation in Mixed Halide Perovskites
T2 - ACS Energy Letters
AU - Brennan, Michael C
AU - Draguta, Sergiu
AU - Kamat, Prashant V
AU - Kuno, Masaru
PY - 2017
DA - 2017/12/22
PB - American Chemical Society (ACS)
SP - 204-213
IS - 1
VL - 3
SN - 2380-8195
ER -
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BibTex (до 50 авторов)
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@article{2017_Brennan,
author = {Michael C Brennan and Sergiu Draguta and Prashant V Kamat and Masaru Kuno},
title = {Light-Induced Anion Phase Segregation in Mixed Halide Perovskites},
journal = {ACS Energy Letters},
year = {2017},
volume = {3},
publisher = {American Chemical Society (ACS)},
month = {dec},
url = {https://doi.org/10.1021/acsenergylett.7b01151},
number = {1},
pages = {204--213},
doi = {10.1021/acsenergylett.7b01151}
}
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MLA
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Brennan, Michael C., et al. “Light-Induced Anion Phase Segregation in Mixed Halide Perovskites.” ACS Energy Letters, vol. 3, no. 1, Dec. 2017, pp. 204-213. https://doi.org/10.1021/acsenergylett.7b01151.
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