том 3 издание 9 страницы 2045-2051

Trends in Activity and Dissolution on RuO2 under Oxygen Evolution Conditions: Particles versus Well-Defined Extended Surfaces

Тип публикацииJournal Article
Дата публикации2018-08-01
scimago Q1
wos Q1
БС1
SJR6.799
CiteScore29.6
Impact factor18.2
ISSN23808195
Materials Chemistry
Chemistry (miscellaneous)
Energy Engineering and Power Technology
Fuel Technology
Renewable Energy, Sustainability and the Environment
Краткое описание
Rutile RuO2 catalysts are the most active pure metal oxides for oxygen evolution; however, they are also unstable toward dissolution. Herein, we study the catalytic activity and stability of oriented thin films of RuO2 with (111), (101), and (001) orientations, in comparison to a (110) single crystal and commercial nanoparticles. These surfaces were all tested in aqueous solutions of 0.05 M H2SO4. The initial catalyst activity ranked as follows: (001) > (101) > (111) ≈ (110). We complemented our activity data with inductively coupled plasma mass spectroscopy, to measure Ru dissolution products occurring in parallel to oxygen evolution. In contrast to earlier reports, we find that, under our experimental conditions, there is no correlation between the activity and stability.
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ГОСТ |
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Roy C. et al. Trends in Activity and Dissolution on RuO2 under Oxygen Evolution Conditions: Particles versus Well-Defined Extended Surfaces // ACS Energy Letters. 2018. Vol. 3. No. 9. pp. 2045-2051.
ГОСТ со всеми авторами (до 50) Скопировать
Roy C., Rao R., Stoerzinger K. A., Hwang J., Rossmeisl J., Chorkendorff I., Shao-Horn Y., Stephens I. E. L. Trends in Activity and Dissolution on RuO2 under Oxygen Evolution Conditions: Particles versus Well-Defined Extended Surfaces // ACS Energy Letters. 2018. Vol. 3. No. 9. pp. 2045-2051.
RIS |
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TY - JOUR
DO - 10.1021/acsenergylett.8b01178
UR - https://doi.org/10.1021/acsenergylett.8b01178
TI - Trends in Activity and Dissolution on RuO2 under Oxygen Evolution Conditions: Particles versus Well-Defined Extended Surfaces
T2 - ACS Energy Letters
AU - Roy, Claudie
AU - Rao, Reshma
AU - Stoerzinger, Kelsey A.
AU - Hwang, Jonathan
AU - Rossmeisl, Jan
AU - Chorkendorff, Ib
AU - Shao-Horn, Yang
AU - Stephens, Ifan E. L.
PY - 2018
DA - 2018/08/01
PB - American Chemical Society (ACS)
SP - 2045-2051
IS - 9
VL - 3
SN - 2380-8195
ER -
BibTex |
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@article{2018_Roy,
author = {Claudie Roy and Reshma Rao and Kelsey A. Stoerzinger and Jonathan Hwang and Jan Rossmeisl and Ib Chorkendorff and Yang Shao-Horn and Ifan E. L. Stephens},
title = {Trends in Activity and Dissolution on RuO2 under Oxygen Evolution Conditions: Particles versus Well-Defined Extended Surfaces},
journal = {ACS Energy Letters},
year = {2018},
volume = {3},
publisher = {American Chemical Society (ACS)},
month = {aug},
url = {https://doi.org/10.1021/acsenergylett.8b01178},
number = {9},
pages = {2045--2051},
doi = {10.1021/acsenergylett.8b01178}
}
MLA
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Roy, Claudie, et al. “Trends in Activity and Dissolution on RuO2 under Oxygen Evolution Conditions: Particles versus Well-Defined Extended Surfaces.” ACS Energy Letters, vol. 3, no. 9, Aug. 2018, pp. 2045-2051. https://doi.org/10.1021/acsenergylett.8b01178.