Synthesis, Characterization, and Reactivity of N-Alkyl Phenoxazines in Organocatalyzed Atom Transfer Radical Polymerization
Publication type: Journal Article
Publication date: 2021-03-26
scimago Q1
wos Q1
SJR: 1.287
CiteScore: 8.9
Impact factor: 5.2
ISSN: 21611653
PubMed ID:
34306819
Materials Chemistry
Organic Chemistry
Inorganic Chemistry
Polymers and Plastics
Abstract
Core-modified N-alkyl phenoxazines were synthesized and evaluated as photoredox catalysts (PCs) in organocatalyzed atom transfer radical polymerization (O-ATRP). Each PC was characterized and found to strongly absorb UVA and visible light, undergo reversible oxidation to radical cation species, and exhibit high quantum yields of fluorescence (Φf > 77%). PCs found to exhibit intramolecular charge transfer in their excited state were capable of the controlled synthesis of poly(methyl methacrylate) with good molecular weight control (I* ~ 100%) and moderately low dispersity (Đ < 1.30).
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19
Total citations:
19
Citations from 2024:
6
(31.58%)
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Swisher N. A., Corbin D. A., Miyake G. M. Synthesis, Characterization, and Reactivity of N-Alkyl Phenoxazines in Organocatalyzed Atom Transfer Radical Polymerization // ACS Macro Letters. 2021. Vol. 10. No. 4. pp. 453-459.
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Swisher N. A., Corbin D. A., Miyake G. M. Synthesis, Characterization, and Reactivity of N-Alkyl Phenoxazines in Organocatalyzed Atom Transfer Radical Polymerization // ACS Macro Letters. 2021. Vol. 10. No. 4. pp. 453-459.
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RIS
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TY - JOUR
DO - 10.1021/acsmacrolett.1c00055
UR - https://doi.org/10.1021/acsmacrolett.1c00055
TI - Synthesis, Characterization, and Reactivity of N-Alkyl Phenoxazines in Organocatalyzed Atom Transfer Radical Polymerization
T2 - ACS Macro Letters
AU - Swisher, Nicholas A
AU - Corbin, Daniel A
AU - Miyake, Garret M.
PY - 2021
DA - 2021/03/26
PB - American Chemical Society (ACS)
SP - 453-459
IS - 4
VL - 10
PMID - 34306819
SN - 2161-1653
ER -
Cite this
BibTex (up to 50 authors)
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@article{2021_Swisher,
author = {Nicholas A Swisher and Daniel A Corbin and Garret M. Miyake},
title = {Synthesis, Characterization, and Reactivity of N-Alkyl Phenoxazines in Organocatalyzed Atom Transfer Radical Polymerization},
journal = {ACS Macro Letters},
year = {2021},
volume = {10},
publisher = {American Chemical Society (ACS)},
month = {mar},
url = {https://doi.org/10.1021/acsmacrolett.1c00055},
number = {4},
pages = {453--459},
doi = {10.1021/acsmacrolett.1c00055}
}
Cite this
MLA
Copy
Swisher, Nicholas A., et al. “Synthesis, Characterization, and Reactivity of N-Alkyl Phenoxazines in Organocatalyzed Atom Transfer Radical Polymerization.” ACS Macro Letters, vol. 10, no. 4, Mar. 2021, pp. 453-459. https://doi.org/10.1021/acsmacrolett.1c00055.