ACS Macro Letters, volume 11, issue 7, pages 941-947
Two-in-One: Photothermal Ring-Opening Copolymerization of CO2 and Epoxides
Publication type: Journal Article
Publication date: 2022-07-11
Materials Chemistry
Organic Chemistry
Inorganic Chemistry
Polymers and Plastics
Abstract
A two-in-one strategy for the photothermal ring-opening copolymerization (PROCOP) of carbon dioxide (CO2) and epoxides was developed by using visible light as an external stimulus. This strategy bridges two processes involving light-to-heat conversion and the alternating copolymerization of CO2 and epoxides. As a proof-of-concept, aluminum porphyrin complexes were explored as photothermal catalysts to afford the copolymerization of CO2/epoxides under a 635 nm laser irradiation. We demonstrated photothermally enhanced polymerization activity, in which the polymerization initiated by the photothermal effect showed a much higher turnover frequency than in the thermal system. Moreover, the PROCOP demonstrated a spatial-temporal control by a light on/off switch. This study provides a fascinating photothermal strategy not only for the CO2/epoxides copolymerization but also for the ring-opening (co)polymerization of other cyclic monomers.
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Zhuo C. et al. Two-in-One: Photothermal Ring-Opening Copolymerization of CO2 and Epoxides // ACS Macro Letters. 2022. Vol. 11. No. 7. pp. 941-947.
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Zhuo C., Cao H., You H., Liu S., Wang X., Wang F. Two-in-One: Photothermal Ring-Opening Copolymerization of CO2 and Epoxides // ACS Macro Letters. 2022. Vol. 11. No. 7. pp. 941-947.
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TY - JOUR
DO - 10.1021/acsmacrolett.2c00365
UR - https://doi.org/10.1021/acsmacrolett.2c00365
TI - Two-in-One: Photothermal Ring-Opening Copolymerization of CO2 and Epoxides
T2 - ACS Macro Letters
AU - Zhuo, Chunwei
AU - Cao, Han
AU - You, Huai
AU - Liu, Shunjie
AU - Wang, Xianhong
AU - Wang, Fosong
PY - 2022
DA - 2022/07/11
PB - American Chemical Society (ACS)
SP - 941-947
IS - 7
VL - 11
SN - 2161-1653
ER -
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@article{2022_Zhuo,
author = {Chunwei Zhuo and Han Cao and Huai You and Shunjie Liu and Xianhong Wang and Fosong Wang},
title = {Two-in-One: Photothermal Ring-Opening Copolymerization of CO2 and Epoxides},
journal = {ACS Macro Letters},
year = {2022},
volume = {11},
publisher = {American Chemical Society (ACS)},
month = {jul},
url = {https://doi.org/10.1021/acsmacrolett.2c00365},
number = {7},
pages = {941--947},
doi = {10.1021/acsmacrolett.2c00365}
}
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Zhuo, Chunwei, et al. “Two-in-One: Photothermal Ring-Opening Copolymerization of CO2 and Epoxides.” ACS Macro Letters, vol. 11, no. 7, Jul. 2022, pp. 941-947. https://doi.org/10.1021/acsmacrolett.2c00365.