Unique Base-Initiated Depolymerization of Limonene-Derived Polycarbonates
2
Dutch Polymer Institute DPI, P.O. Box 902, 5600 AX Eindhoven, The Netherlands
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3
Polymer Technology
Group Eindhoven B.V. (PTG/e B.V.) P.O. Box 6284, 5600 HG Eindhoven, The Netherlands
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4
DSM Ahead
BV Urmonderbaan 22, 6167
RG Geleen, The Netherlands
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5
DSM Coating
Resins Ceintuurbaan 5, 8022
AW Zwolle, The Netherlands
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Publication type: Journal Article
Publication date: 2017-06-15
scimago Q1
wos Q1
SJR: 1.287
CiteScore: 8.9
Impact factor: 5.2
ISSN: 21611653
PubMed ID:
35650870
Materials Chemistry
Organic Chemistry
Inorganic Chemistry
Polymers and Plastics
Abstract
The depolymerization of poly(limonene carbonate) (PLC) initiated by 1,5,7-triazabicyclo[4.4.0]dec-5-ene (TBD) was investigated. The strong organic base TBD was capable of deprotonating the OH-terminated PLC, leading to fast degradation via backbiting reactions at high temperature. An interesting feature of the base-initiated breakdown of PLC lies in the quantitative depolymerization into the corresponding initial limonene oxide monomer. This result implies the complete back-to-monomer recyclability of the fully biobased PLC, which accordingly can be considered as a really sustainable material. Additionally, the stability of PLC when exposed to TBD was enhanced by an end-capping reaction, which further supported the proposed degradation pathway.
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101
Total citations:
101
Citations from 2024:
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(29%)
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GOST
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Li C. et al. Unique Base-Initiated Depolymerization of Limonene-Derived Polycarbonates // ACS Macro Letters. 2017. Vol. 6. No. 7. pp. 684-688.
GOST all authors (up to 50)
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Li C., Sablong R. J., van Benthem R. A., Koning C. Unique Base-Initiated Depolymerization of Limonene-Derived Polycarbonates // ACS Macro Letters. 2017. Vol. 6. No. 7. pp. 684-688.
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RIS
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TY - JOUR
DO - 10.1021/acsmacrolett.7b00310
UR - https://doi.org/10.1021/acsmacrolett.7b00310
TI - Unique Base-Initiated Depolymerization of Limonene-Derived Polycarbonates
T2 - ACS Macro Letters
AU - Li, Chunliang
AU - Sablong, Rafaël J
AU - van Benthem, Rolf A.T.M
AU - Koning, C.E.
PY - 2017
DA - 2017/06/15
PB - American Chemical Society (ACS)
SP - 684-688
IS - 7
VL - 6
PMID - 35650870
SN - 2161-1653
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2017_Li,
author = {Chunliang Li and Rafaël J Sablong and Rolf A.T.M van Benthem and C.E. Koning},
title = {Unique Base-Initiated Depolymerization of Limonene-Derived Polycarbonates},
journal = {ACS Macro Letters},
year = {2017},
volume = {6},
publisher = {American Chemical Society (ACS)},
month = {jun},
url = {https://doi.org/10.1021/acsmacrolett.7b00310},
number = {7},
pages = {684--688},
doi = {10.1021/acsmacrolett.7b00310}
}
Cite this
MLA
Copy
Li, Chunliang, et al. “Unique Base-Initiated Depolymerization of Limonene-Derived Polycarbonates.” ACS Macro Letters, vol. 6, no. 7, Jun. 2017, pp. 684-688. https://doi.org/10.1021/acsmacrolett.7b00310.