ACS Macro Letters, volume 6, issue 7, pages 684-688
Unique Base-Initiated Depolymerization of Limonene-Derived Polycarbonates
2
Dutch Polymer Institute DPI, P.O. Box 902, 5600 AX Eindhoven, The Netherlands
|
3
Polymer Technology
Group Eindhoven B.V. (PTG/e B.V.) P.O. Box 6284, 5600 HG Eindhoven, The Netherlands
|
4
DSM Ahead
BV Urmonderbaan 22, 6167
RG Geleen, The Netherlands
|
5
DSM Coating
Resins Ceintuurbaan 5, 8022
AW Zwolle, The Netherlands
|
Publication type: Journal Article
Publication date: 2017-06-15
Materials Chemistry
Organic Chemistry
Inorganic Chemistry
Polymers and Plastics
Abstract
The depolymerization of poly(limonene carbonate) (PLC) initiated by 1,5,7-triazabicyclo[4.4.0]dec-5-ene (TBD) was investigated. The strong organic base TBD was capable of deprotonating the OH-terminated PLC, leading to fast degradation via backbiting reactions at high temperature. An interesting feature of the base-initiated breakdown of PLC lies in the quantitative depolymerization into the corresponding initial limonene oxide monomer. This result implies the complete back-to-monomer recyclability of the fully biobased PLC, which accordingly can be considered as a really sustainable material. Additionally, the stability of PLC when exposed to TBD was enhanced by an end-capping reaction, which further supported the proposed degradation pathway.
Found
Found
Top-30
Journals
|
2
4
6
8
10
|
|
|
Polymer Chemistry
10 publications, 11.11%
|
|
|
ACS Macro Letters
7 publications, 7.78%
|
|
|
Macromolecules
6 publications, 6.67%
|
|
|
Angewandte Chemie
6 publications, 6.67%
|
|
|
Angewandte Chemie - International Edition
6 publications, 6.67%
|
|
|
Journal of the American Chemical Society
5 publications, 5.56%
|
|
|
Green Chemistry
4 publications, 4.44%
|
|
|
Chemistry - A European Journal
3 publications, 3.33%
|
|
|
Journal of Polymer Science
3 publications, 3.33%
|
|
|
Science China Chemistry
2 publications, 2.22%
|
|
|
Nature Reviews Materials
2 publications, 2.22%
|
|
|
Polymer Degradation and Stability
2 publications, 2.22%
|
|
|
ACS Catalysis
2 publications, 2.22%
|
|
|
Chemical Science
2 publications, 2.22%
|
|
|
ACS Sustainable Chemistry and Engineering
2 publications, 2.22%
|
|
|
RSC Sustainability
2 publications, 2.22%
|
|
|
Chemical Reviews
2 publications, 2.22%
|
|
|
Fundamental Research
2 publications, 2.22%
|
|
|
Chemistry - An Asian Journal
1 publication, 1.11%
|
|
|
Acta Chimica Sinica
1 publication, 1.11%
|
|
|
Cell Reports Physical Science
1 publication, 1.11%
|
|
|
Green Chemical Engineering
1 publication, 1.11%
|
|
|
Carbohydrate Polymers
1 publication, 1.11%
|
|
|
European Polymer Journal
1 publication, 1.11%
|
|
|
Progress in Organic Coatings
1 publication, 1.11%
|
|
|
Macromolecular Chemistry and Physics
1 publication, 1.11%
|
|
|
Polymer Reviews
1 publication, 1.11%
|
|
|
Polymer International
1 publication, 1.11%
|
|
|
Macromolecular Materials and Engineering
1 publication, 1.11%
|
|
|
2
4
6
8
10
|
Publishers
|
5
10
15
20
25
30
|
|
|
Wiley
26 publications, 28.89%
|
|
|
American Chemical Society (ACS)
25 publications, 27.78%
|
|
|
Royal Society of Chemistry (RSC)
19 publications, 21.11%
|
|
|
Elsevier
10 publications, 11.11%
|
|
|
Springer Nature
5 publications, 5.56%
|
|
|
Shanghai Institute of Organic Chemistry
1 publication, 1.11%
|
|
|
Taylor & Francis
1 publication, 1.11%
|
|
|
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 1.11%
|
|
|
MDPI
1 publication, 1.11%
|
|
|
5
10
15
20
25
30
|
- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
Are you a researcher?
Create a profile to get free access to personal recommendations for colleagues and new articles.
Metrics
Cite this
GOST |
RIS |
BibTex |
MLA
Cite this
GOST
Copy
Li C. et al. Unique Base-Initiated Depolymerization of Limonene-Derived Polycarbonates // ACS Macro Letters. 2017. Vol. 6. No. 7. pp. 684-688.
GOST all authors (up to 50)
Copy
Li C., Sablong R. J., van Benthem R. A., Koning C. Unique Base-Initiated Depolymerization of Limonene-Derived Polycarbonates // ACS Macro Letters. 2017. Vol. 6. No. 7. pp. 684-688.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/acsmacrolett.7b00310
UR - https://doi.org/10.1021/acsmacrolett.7b00310
TI - Unique Base-Initiated Depolymerization of Limonene-Derived Polycarbonates
T2 - ACS Macro Letters
AU - Li, Chunliang
AU - Sablong, Rafaël J
AU - van Benthem, Rolf A.T.M
AU - Koning, C.E.
PY - 2017
DA - 2017/06/15
PB - American Chemical Society (ACS)
SP - 684-688
IS - 7
VL - 6
SN - 2161-1653
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2017_Li,
author = {Chunliang Li and Rafaël J Sablong and Rolf A.T.M van Benthem and C.E. Koning},
title = {Unique Base-Initiated Depolymerization of Limonene-Derived Polycarbonates},
journal = {ACS Macro Letters},
year = {2017},
volume = {6},
publisher = {American Chemical Society (ACS)},
month = {jun},
url = {https://doi.org/10.1021/acsmacrolett.7b00310},
number = {7},
pages = {684--688},
doi = {10.1021/acsmacrolett.7b00310}
}
Cite this
MLA
Copy
Li, Chunliang, et al. “Unique Base-Initiated Depolymerization of Limonene-Derived Polycarbonates.” ACS Macro Letters, vol. 6, no. 7, Jun. 2017, pp. 684-688. https://doi.org/10.1021/acsmacrolett.7b00310.