Open Access
ACS Omega, volume 5, issue 45, pages 29570-29576
Thermogravimetric Determination of the Kinetics of Petroleum Needle Coke Formation by Decantoil Thermolysis
2
Instituto Mexicano del Petroleo, Mexico City 07730, Mexico
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Publication type: Journal Article
Publication date: 2020-11-05
PubMed ID:
33225188
General Chemistry
General Chemical Engineering
Abstract
This work presents the results of thermogravimetric analysis of decantoil. The microstructure of the extracted petroleum coke during the thermolysis of decantoil in an inert nitrogen atmosphere at 1000 °C was studied by scanning electron microscopy and interpreted as acicular. The model free kinetic approach based on Friedman’s isoconversion method was used to calculate the kinetic characteristics of decantoil thermolysis-activation energy and pre-exponential factor. The individual hydrocarbon composition of decantoil was determined by gas chromatography mass spectrometry, which was used to determine the activation energy of evaporation of its fractions. The total energy spent on the chemical reactions of cracking and thermopolycondensation was determined when the degree of decantoil conversion was changed from 0.1 to 0.9.
Citations by journals
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1
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Symmetry
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Symmetry
1 publication, 16.67%
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Mathematics
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Mathematics
1 publication, 16.67%
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Energy Sources, Part A: Recovery, Utilization and Environmental Effects
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Energy Sources, Part A: Recovery, Utilization and Environmental Effects
1 publication, 16.67%
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Water Science and Technology
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Water Science and Technology
1 publication, 16.67%
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Petroleum Engineering
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Petroleum Engineering
1 publication, 16.67%
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Canadian Journal of Chemical Engineering
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Canadian Journal of Chemical Engineering
1 publication, 16.67%
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1
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Citations by publishers
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1
2
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Multidisciplinary Digital Publishing Institute (MDPI)
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Multidisciplinary Digital Publishing Institute (MDPI)
2 publications, 33.33%
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Taylor & Francis
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Taylor & Francis
1 publication, 16.67%
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IWA Publishing
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IWA Publishing
1 publication, 16.67%
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Ufa State Petroleum Technological University
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Ufa State Petroleum Technological University
1 publication, 16.67%
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Wiley
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Wiley
1 publication, 16.67%
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1
2
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- We do not take into account publications that without a DOI.
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- Statistics recalculated weekly.
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Kondrasheva N. K., Rudko V. A., Ancheyta J. Thermogravimetric Determination of the Kinetics of Petroleum Needle Coke Formation by Decantoil Thermolysis // ACS Omega. 2020. Vol. 5. No. 45. pp. 29570-29576.
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Kondrasheva N. K., Rudko V. A., Ancheyta J. Thermogravimetric Determination of the Kinetics of Petroleum Needle Coke Formation by Decantoil Thermolysis // ACS Omega. 2020. Vol. 5. No. 45. pp. 29570-29576.
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TY - JOUR
DO - 10.1021/acsomega.0c04552
UR - https://doi.org/10.1021%2Facsomega.0c04552
TI - Thermogravimetric Determination of the Kinetics of Petroleum Needle Coke Formation by Decantoil Thermolysis
T2 - ACS Omega
AU - Kondrasheva, Natalia K
AU - Rudko, Viacheslav A
AU - Ancheyta, J.
PY - 2020
DA - 2020/11/05 00:00:00
PB - American Chemical Society (ACS)
SP - 29570-29576
IS - 45
VL - 5
PMID - 33225188
SN - 2470-1343
ER -
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@article{2020_Kondrasheva,
author = {Natalia K Kondrasheva and Viacheslav A Rudko and J. Ancheyta},
title = {Thermogravimetric Determination of the Kinetics of Petroleum Needle Coke Formation by Decantoil Thermolysis},
journal = {ACS Omega},
year = {2020},
volume = {5},
publisher = {American Chemical Society (ACS)},
month = {nov},
url = {https://doi.org/10.1021%2Facsomega.0c04552},
number = {45},
pages = {29570--29576},
doi = {10.1021/acsomega.0c04552}
}
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Kondrasheva, Natalia K., et al. “Thermogravimetric Determination of the Kinetics of Petroleum Needle Coke Formation by Decantoil Thermolysis.” ACS Omega, vol. 5, no. 45, Nov. 2020, pp. 29570-29576. https://doi.org/10.1021%2Facsomega.0c04552.