Open Access
Thermogravimetric Determination of the Kinetics of Petroleum Needle Coke Formation by Decantoil Thermolysis
Publication type: Journal Article
Publication date: 2020-11-05
scimago Q1
wos Q2
SJR: 0.773
CiteScore: 7.1
Impact factor: 4.3
ISSN: 24701343
PubMed ID:
33225188
General Chemistry
General Chemical Engineering
Abstract
This work presents the results of thermogravimetric analysis of decantoil. The microstructure of the extracted petroleum coke during the thermolysis of decantoil in an inert nitrogen atmosphere at 1000 °C was studied by scanning electron microscopy and interpreted as acicular. The model free kinetic approach based on Friedman’s isoconversion method was used to calculate the kinetic characteristics of decantoil thermolysis-activation energy and pre-exponential factor. The individual hydrocarbon composition of decantoil was determined by gas chromatography mass spectrometry, which was used to determine the activation energy of evaporation of its fractions. The total energy spent on the chemical reactions of cracking and thermopolycondensation was determined when the degree of decantoil conversion was changed from 0.1 to 0.9.
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15
Total citations:
15
Citations from 2024:
10
(66%)
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GOST
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Kondrasheva N. K., Rudko V. A., Ancheyta J. Thermogravimetric Determination of the Kinetics of Petroleum Needle Coke Formation by Decantoil Thermolysis // ACS Omega. 2020. Vol. 5. No. 45. pp. 29570-29576.
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Kondrasheva N. K., Rudko V. A., Ancheyta J. Thermogravimetric Determination of the Kinetics of Petroleum Needle Coke Formation by Decantoil Thermolysis // ACS Omega. 2020. Vol. 5. No. 45. pp. 29570-29576.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/acsomega.0c04552
UR - https://doi.org/10.1021/acsomega.0c04552
TI - Thermogravimetric Determination of the Kinetics of Petroleum Needle Coke Formation by Decantoil Thermolysis
T2 - ACS Omega
AU - Kondrasheva, Natalia K
AU - Rudko, Viacheslav A
AU - Ancheyta, J.
PY - 2020
DA - 2020/11/05
PB - American Chemical Society (ACS)
SP - 29570-29576
IS - 45
VL - 5
PMID - 33225188
SN - 2470-1343
ER -
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BibTex (up to 50 authors)
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@article{2020_Kondrasheva,
author = {Natalia K Kondrasheva and Viacheslav A Rudko and J. Ancheyta},
title = {Thermogravimetric Determination of the Kinetics of Petroleum Needle Coke Formation by Decantoil Thermolysis},
journal = {ACS Omega},
year = {2020},
volume = {5},
publisher = {American Chemical Society (ACS)},
month = {nov},
url = {https://doi.org/10.1021/acsomega.0c04552},
number = {45},
pages = {29570--29576},
doi = {10.1021/acsomega.0c04552}
}
Cite this
MLA
Copy
Kondrasheva, Natalia K., et al. “Thermogravimetric Determination of the Kinetics of Petroleum Needle Coke Formation by Decantoil Thermolysis.” ACS Omega, vol. 5, no. 45, Nov. 2020, pp. 29570-29576. https://doi.org/10.1021/acsomega.0c04552.