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ACS Omega

, том 5 , издание 45 , страницы 29570-29576

Thermogravimetric Determination of the Kinetics of Petroleum Needle Coke Formation by Decantoil Thermolysis

Тип публикации: Journal Article

Дата публикации: 2020-11-05

American Chemical Society (ACS)

ACS Omega

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SJR: 0.805

CiteScore: 7.8

Impact factor: 5.2

ISSN: 24701343

DOI: 10.1021/acsomega.0c04552

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PubMed ID: 33225188

General Chemistry

General Chemical Engineering

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This work presents the results of thermogravimetric analysis of decantoil. The microstructure of the extracted petroleum coke during the thermolysis of decantoil in an inert nitrogen atmosphere at 1000 °C was studied by scanning electron microscopy and interpreted as acicular. The model free kinetic approach based on Friedman’s isoconversion method was used to calculate the kinetic characteristics of decantoil thermolysis-activation energy and pre-exponential factor. The individual hydrocarbon composition of decantoil was determined by gas chromatography mass spectrometry, which was used to determine the activation energy of evaporation of its fractions. The total energy spent on the chemical reactions of cracking and thermopolycondensation was determined when the degree of decantoil conversion was changed from 0.1 to 0.9.

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Kondrasheva N. K., Rudko V. A., Ancheyta J. Thermogravimetric Determination of the Kinetics of Petroleum Needle Coke Formation by Decantoil Thermolysis // ACS Omega. 2020. Vol. 5. No. 45. pp. 29570-29576.

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TY - JOUR

DO - 10.1021/acsomega.0c04552

UR - https://doi.org/10.1021/acsomega.0c04552

TI - Thermogravimetric Determination of the Kinetics of Petroleum Needle Coke Formation by Decantoil Thermolysis

T2 - ACS Omega

AU - Kondrasheva, Natalia K

AU - Rudko, Viacheslav A

AU - Ancheyta, J.

PY - 2020

DA - 2020/11/05

PB - American Chemical Society (ACS)

SP - 29570-29576

IS - 45

VL - 5

PMID - 33225188

SN - 2470-1343

ER -

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@article{2020_Kondrasheva,

author = {Natalia K Kondrasheva and Viacheslav A Rudko and J. Ancheyta},

title = {Thermogravimetric Determination of the Kinetics of Petroleum Needle Coke Formation by Decantoil Thermolysis},

journal = {ACS Omega},

year = {2020},

volume = {5},

publisher = {American Chemical Society (ACS)},

month = {nov},

url = {https://doi.org/10.1021/acsomega.0c04552},

number = {45},

pages = {29570--29576},

doi = {10.1021/acsomega.0c04552}

}

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Kondrasheva, Natalia K., et al. “Thermogravimetric Determination of the Kinetics of Petroleum Needle Coke Formation by Decantoil Thermolysis.” ACS Omega, vol. 5, no. 45, Nov. 2020, pp. 29570-29576. https://doi.org/10.1021/acsomega.0c04552.

Издатель

American Chemical Society (ACS)

Журнал

ACS Omega

SCImago Q1

WOS Q2

БС1

SJR

0.805

CiteScore

7.8

Impact factor