ACS Sustainable Chemistry and Engineering

, volume 9 , issue 17 , pages 6118-6125

From Reactive Oxygen Species to Reactive Brominating Species: Fenton Chemistry for Oxidative Bromination

Guodong Zhao ^{1, 2}

Eryu Wang ²

Rong-Biao Tong ^{2, 3, 4}

Hide authors affiliations Show authors affiliations: 4 affiliations

School of Chinese Materia Medica, Beijing University of Chinese Medicine, Yangguang South Avenue, Fangshan District, Beijing 102488, China |

Department of Chemistry, The Hong Kong University of Science and Technology, Clearwater Bay, Kowloon, Hong Kong 999077, China |

Hong Kong Branch of the Guangdong Southern Marine Science and Engineering Laboratory (Guangzhou), The Hong Kong University of Science and Technology, Clearwater Bay, Kowloon, Hong Kong 999077, China |

⁴

HKUST Shenzhen Research Institute, No. 9 Yuexing First RD, Nanshan District, Shenzhen 518057, China |

Publication type: Journal Article

Publication date: 2021-04-16

American Chemical Society (ACS)

ACS Sustainable Chemistry and Engineering

scimago Q1

wos Q1

SJR: 1.623

CiteScore: 12.5

Impact factor: 7.3

ISSN: 21680485

DOI: 10.1021/acssuschemeng.1c01709

Copy DOI

General Chemistry

General Chemical Engineering

Environmental Chemistry

Renewable Energy, Sustainability and the Environment

Abstract

Fenton chemistry (Feᴵᴵ + H₂O₂ → HO•/HOO• + H₂O) generates reactive oxygen species (ROS) that are used for treatment of wastewater and oxidation of organic molecules and play a key role in biological oxidation systems. This study shows that Fenton chemistry can be used for generation of reactive brominating species (RBS) under neutral conditions at room temperature. The in situ RBS are successfully used for three types of oxidative bromination reactions. This green and nonacidic new method addresses the safety and environmental challenges of existing oxidative bromination methods. Additionally, this neutral Fenton–bromide system addresses the long-lasting problem of many functional haloperoxidase mimics that required strong acids for oxidation of bromide ion with hydrogen peroxide. This new green and mild method for generating RBS will significantly benefit the wide applications of brominated organic compounds in organic synthesis and the fine chemical and pharmaceutical industries.

Found

1 citation

Dinesh Dr.

11 publications, 26 citations, 2 reviews

h-index: 3

Guru Ghasidas Vishwavidyalaya

Research interests

Nanocomposites

Top-30

Journals

	1 2 3 4 5
Journal of Organic Chemistry	Journal of Organic Chemistry, 5, 13.51% Journal of Organic Chemistry 5 publications, 13.51%
Organic Letters	Organic Letters, 4, 10.81% Organic Letters 4 publications, 10.81%
Tetrahedron	Tetrahedron, 3, 8.11% Tetrahedron 3 publications, 8.11%
Green Chemistry	Green Chemistry, 3, 8.11% Green Chemistry 3 publications, 8.11%
Organic and Biomolecular Chemistry	Organic and Biomolecular Chemistry, 2, 5.41% Organic and Biomolecular Chemistry 2 publications, 5.41%
Advanced Synthesis and Catalysis	Advanced Synthesis and Catalysis, 2, 5.41% Advanced Synthesis and Catalysis 2 publications, 5.41%
Tetrahedron Letters	Tetrahedron Letters, 1, 2.7% Tetrahedron Letters 1 publication, 2.7%
Mendeleev Communications	Mendeleev Communications, 1, 2.7% Mendeleev Communications 1 publication, 2.7%
Plasma Processes and Polymers	Plasma Processes and Polymers, 1, 2.7% Plasma Processes and Polymers 1 publication, 2.7%
European Journal of Organic Chemistry	European Journal of Organic Chemistry, 1, 2.7% European Journal of Organic Chemistry 1 publication, 2.7%
Accounts of Chemical Research	Accounts of Chemical Research, 1, 2.7% Accounts of Chemical Research 1 publication, 2.7%
ACS Materials Letters	ACS Materials Letters, 1, 2.7% ACS Materials Letters 1 publication, 2.7%
RSC Advances	RSC Advances, 1, 2.7% RSC Advances 1 publication, 2.7%
Chinese Chemical Letters	Chinese Chemical Letters, 1, 2.7% Chinese Chemical Letters 1 publication, 2.7%
ACS Omega	ACS Omega, 1, 2.7% ACS Omega 1 publication, 2.7%
Advances in Science, Technology & Innovation	Advances in Science, Technology & Innovation, 1, 2.7% Advances in Science, Technology & Innovation 1 publication, 2.7%
Nature Communications	Nature Communications, 1, 2.7% Nature Communications 1 publication, 2.7%
Science advances	Science advances, 1, 2.7% Science advances 1 publication, 2.7%
Analytical Methods	Analytical Methods, 1, 2.7% Analytical Methods 1 publication, 2.7%
Journal of the American Chemical Society	Journal of the American Chemical Society, 1, 2.7% Journal of the American Chemical Society 1 publication, 2.7%
Angewandte Chemie - International Edition	Angewandte Chemie - International Edition, 1, 2.7% Angewandte Chemie - International Edition 1 publication, 2.7%
Angewandte Chemie	Angewandte Chemie, 1, 2.7% Angewandte Chemie 1 publication, 2.7%
Dalton Transactions	Dalton Transactions, 1, 2.7% Dalton Transactions 1 publication, 2.7%
RSC Mechanochemistry	RSC Mechanochemistry, 1, 2.7% RSC Mechanochemistry 1 publication, 2.7%
	1 2 3 4 5

Publishers

	2 4 6 8 10 12 14
American Chemical Society (ACS)	American Chemical Society (ACS), 13, 35.14% American Chemical Society (ACS) 13 publications, 35.14%
Royal Society of Chemistry (RSC)	Royal Society of Chemistry (RSC), 9, 24.32% Royal Society of Chemistry (RSC) 9 publications, 24.32%
Wiley	Wiley, 6, 16.22% Wiley 6 publications, 16.22%
Elsevier	Elsevier, 5, 13.51% Elsevier 5 publications, 13.51%
Springer Nature	Springer Nature, 2, 5.41% Springer Nature 2 publications, 5.41%
OOO Zhurnal "Mendeleevskie Soobshcheniya"	OOO Zhurnal "Mendeleevskie Soobshcheniya", 1, 2.7% OOO Zhurnal "Mendeleevskie Soobshcheniya" 1 publication, 2.7%
American Association for the Advancement of Science (AAAS)	American Association for the Advancement of Science (AAAS), 1, 2.7% American Association for the Advancement of Science (AAAS) 1 publication, 2.7%
	2 4 6 8 10 12 14

We do not take into account publications without a DOI.
Statistics recalculated weekly.

Are you a researcher?

Create a profile to get free access to personal recommendations for colleagues and new articles.

Metrics

Cite this

GOST |

Cite this

GOST Copy

Zhao G. et al. From Reactive Oxygen Species to Reactive Brominating Species: Fenton Chemistry for Oxidative Bromination // ACS Sustainable Chemistry and Engineering. 2021. Vol. 9. No. 17. pp. 6118-6125.

GOST all authors (up to 50) Copy

Zhao G., Wang E., Tong R. From Reactive Oxygen Species to Reactive Brominating Species: Fenton Chemistry for Oxidative Bromination // ACS Sustainable Chemistry and Engineering. 2021. Vol. 9. No. 17. pp. 6118-6125.

RIS |

Cite this

RIS Copy

TY - JOUR

DO - 10.1021/acssuschemeng.1c01709

UR - https://doi.org/10.1021/acssuschemeng.1c01709

TI - From Reactive Oxygen Species to Reactive Brominating Species: Fenton Chemistry for Oxidative Bromination

T2 - ACS Sustainable Chemistry and Engineering

AU - Zhao, Guodong

AU - Wang, Eryu

AU - Tong, Rong-Biao

PY - 2021

DA - 2021/04/16

PB - American Chemical Society (ACS)

SP - 6118-6125

IS - 17

VL - 9

SN - 2168-0485

ER -

BibTex |

Cite this

BibTex (up to 50 authors) Copy

@article{2021_Zhao,

author = {Guodong Zhao and Eryu Wang and Rong-Biao Tong},

title = {From Reactive Oxygen Species to Reactive Brominating Species: Fenton Chemistry for Oxidative Bromination},

journal = {ACS Sustainable Chemistry and Engineering},

year = {2021},

volume = {9},

publisher = {American Chemical Society (ACS)},

month = {apr},

url = {https://doi.org/10.1021/acssuschemeng.1c01709},

number = {17},

pages = {6118--6125},

doi = {10.1021/acssuschemeng.1c01709}

}

MLA

Cite this

MLA Copy

Zhao, Guodong, et al. “From Reactive Oxygen Species to Reactive Brominating Species: Fenton Chemistry for Oxidative Bromination.” ACS Sustainable Chemistry and Engineering, vol. 9, no. 17, Apr. 2021, pp. 6118-6125. https://doi.org/10.1021/acssuschemeng.1c01709.

Publisher

American Chemical Society (ACS)

Journal

ACS Sustainable Chemistry and Engineering

scimago Q1

wos Q1

SJR

1.623

CiteScore

12.5

Impact factor

7.3

ISSN

21680485 (Print, Electronic)