ACS Sustainable Chemistry and Engineering, volume 5, issue 5, pages 3871-3881

Carbon Dioxide-Based Polyols as Sustainable Feedstock of Thermoplastic Polyurethane for Corrosion-Resistant Metal Coating

Publication typeJournal Article
Publication date2017-04-12
Q1
Q1
SJR1.664
CiteScore13.8
Impact factor7.1
ISSN21680485
General Chemistry
General Chemical Engineering
Environmental Chemistry
Renewable Energy, Sustainability and the Environment
Abstract
Abundant, inexpensive, renewable, and nontoxic carbon dioxide (CO2) has become an attractive feedstock for chemical and polymer syntheses. The use of CO2 as a sustainable precursor for polyurethane has become prominent in polymer industry. In this study, polyols produced from CO2 were successfully incorporated into thermoplastic polyurethanes (TPUs). The thermal, mechanical, shape memory, and anticorrosion properties of the TPUs were investigated. TPUs with CO2-based polyols appeared as hard plastics with relatively high Tg and tension set values. The rigid carbonate units of the CO2-based polyols reduced the softness of the polyol chains. The CO2-based polyols also afforded TPU with excellent shape memory characteristics, exhibiting shape fixity and shape recovery values of almost 100%. Interestingly, the incorporation of CO2-based polyols into TPUs improved the anticorrosion characteristics, regardless of the corrosive media. The improved anticorrosion characteristics stemmed from the robust, hydrophobi...
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GOST Copy
Alagi P. et al. Carbon Dioxide-Based Polyols as Sustainable Feedstock of Thermoplastic Polyurethane for Corrosion-Resistant Metal Coating // ACS Sustainable Chemistry and Engineering. 2017. Vol. 5. No. 5. pp. 3871-3881.
GOST all authors (up to 50) Copy
Alagi P., Ghorpade R., Choi Y., Patil U., Kim I. S., Baik J. H., Hong S. C. Carbon Dioxide-Based Polyols as Sustainable Feedstock of Thermoplastic Polyurethane for Corrosion-Resistant Metal Coating // ACS Sustainable Chemistry and Engineering. 2017. Vol. 5. No. 5. pp. 3871-3881.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1021/acssuschemeng.6b03046
UR - https://doi.org/10.1021/acssuschemeng.6b03046
TI - Carbon Dioxide-Based Polyols as Sustainable Feedstock of Thermoplastic Polyurethane for Corrosion-Resistant Metal Coating
T2 - ACS Sustainable Chemistry and Engineering
AU - Alagi, Prakash
AU - Ghorpade, Ravindra
AU - Choi, Ye-Jin
AU - Patil, Umakant
AU - Kim, I S
AU - Baik, Joon Hyun
AU - Hong, Sung Chul
PY - 2017
DA - 2017/04/12
PB - American Chemical Society (ACS)
SP - 3871-3881
IS - 5
VL - 5
SN - 2168-0485
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2017_Alagi,
author = {Prakash Alagi and Ravindra Ghorpade and Ye-Jin Choi and Umakant Patil and I S Kim and Joon Hyun Baik and Sung Chul Hong},
title = {Carbon Dioxide-Based Polyols as Sustainable Feedstock of Thermoplastic Polyurethane for Corrosion-Resistant Metal Coating},
journal = {ACS Sustainable Chemistry and Engineering},
year = {2017},
volume = {5},
publisher = {American Chemical Society (ACS)},
month = {apr},
url = {https://doi.org/10.1021/acssuschemeng.6b03046},
number = {5},
pages = {3871--3881},
doi = {10.1021/acssuschemeng.6b03046}
}
MLA
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MLA Copy
Alagi, Prakash, et al. “Carbon Dioxide-Based Polyols as Sustainable Feedstock of Thermoplastic Polyurethane for Corrosion-Resistant Metal Coating.” ACS Sustainable Chemistry and Engineering, vol. 5, no. 5, Apr. 2017, pp. 3871-3881. https://doi.org/10.1021/acssuschemeng.6b03046.
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