volume 6 issue 5 pages 5959-5968

Innovative Application of Acid Leaching to Regenerate Li(Ni1/3Co1/3Mn1/3)O2 Cathodes from Spent Lithium-Ion Batteries

Xiaoxiao Zhang 1
Yifan Bian 1
Siwenyu Xu 1
Ersha Fan 1
Qing Xue 1
Yibiao Guan 2
Feng Wu 1, 3
Li Li 1, 3
2
 
State Key Laboratory of Operation and Control of Renewable Energy & Storage Systems, China Electric Power Research Institute, Beijing 100192, China
3
 
Collaborative Innovation Center of Electric Vehicles in Beijing, Beijing 100081, China
Publication typeJournal Article
Publication date2018-03-19
scimago Q1
wos Q1
SJR1.623
CiteScore12.5
Impact factor7.3
ISSN21680485
General Chemistry
General Chemical Engineering
Environmental Chemistry
Renewable Energy, Sustainability and the Environment
Abstract
Rapid development of energy storage system causes a burst demand of lithium-ion batteries (LIBs), and large number of spent LIBs with high valuable metals are produced. Here we propose a novel application of oxalic acid leaching to regenerate Li(Ni1/3Co1/3Mn1/3)O2 (NCM) cathodes from spent LIBs. With lithium dissolving into the solution, the transition metals transform into oxalate precipitates and deposit on the surface of spent NCM cathodes, separating lithium and transition metals in one simple step. After mixing with certain amount of Li2CO3, the oxalate precipitates together with unreacted NCM are directly calcined into new NCM cathodes. The regenerated NCM after 10 min leaching exhibits the best electrochemical performances, delivering the highest initial specific discharge capacity of 168 mA h g–1 at 0.2C and 153.7 mA h g–1 after 150 cycles with a high capacity retention of 91.5%. The excellent electrochemical performances are attributed to the submicrometer particles and voids after calcination, a...
Found 
Found 

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GOST |
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GOST Copy
Zhang X. et al. Innovative Application of Acid Leaching to Regenerate Li(Ni1/3Co1/3Mn1/3)O2 Cathodes from Spent Lithium-Ion Batteries // ACS Sustainable Chemistry and Engineering. 2018. Vol. 6. No. 5. pp. 5959-5968.
GOST all authors (up to 50) Copy
Zhang X., Bian Y., Xu S., Fan E., Xue Q., Guan Y., Wu F., Li L., Chen R. Innovative Application of Acid Leaching to Regenerate Li(Ni1/3Co1/3Mn1/3)O2 Cathodes from Spent Lithium-Ion Batteries // ACS Sustainable Chemistry and Engineering. 2018. Vol. 6. No. 5. pp. 5959-5968.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1021/acssuschemeng.7b04373
UR - https://doi.org/10.1021/acssuschemeng.7b04373
TI - Innovative Application of Acid Leaching to Regenerate Li(Ni1/3Co1/3Mn1/3)O2 Cathodes from Spent Lithium-Ion Batteries
T2 - ACS Sustainable Chemistry and Engineering
AU - Zhang, Xiaoxiao
AU - Bian, Yifan
AU - Xu, Siwenyu
AU - Fan, Ersha
AU - Xue, Qing
AU - Guan, Yibiao
AU - Wu, Feng
AU - Li, Li
AU - Chen, Renjie
PY - 2018
DA - 2018/03/19
PB - American Chemical Society (ACS)
SP - 5959-5968
IS - 5
VL - 6
SN - 2168-0485
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2018_Zhang,
author = {Xiaoxiao Zhang and Yifan Bian and Siwenyu Xu and Ersha Fan and Qing Xue and Yibiao Guan and Feng Wu and Li Li and Renjie Chen},
title = {Innovative Application of Acid Leaching to Regenerate Li(Ni1/3Co1/3Mn1/3)O2 Cathodes from Spent Lithium-Ion Batteries},
journal = {ACS Sustainable Chemistry and Engineering},
year = {2018},
volume = {6},
publisher = {American Chemical Society (ACS)},
month = {mar},
url = {https://doi.org/10.1021/acssuschemeng.7b04373},
number = {5},
pages = {5959--5968},
doi = {10.1021/acssuschemeng.7b04373}
}
MLA
Cite this
MLA Copy
Zhang, Xiaoxiao, et al. “Innovative Application of Acid Leaching to Regenerate Li(Ni1/3Co1/3Mn1/3)O2 Cathodes from Spent Lithium-Ion Batteries.” ACS Sustainable Chemistry and Engineering, vol. 6, no. 5, Mar. 2018, pp. 5959-5968. https://doi.org/10.1021/acssuschemeng.7b04373.