Inhibition of CO2 Corrosion via Sustainable Geminal Zwitterionic Compounds: Effect of the Length of the Hydrocarbon Chain from Amines
Enrique Gómez Juárez
1
,
Violeta Y Mena Cervantes
1, 2
,
Jorge Vazquez-Arenas
1, 2
,
Gabriel Pineda Flores
1, 2
,
Raúl Hernández Altamirano
1, 2
Publication type: Journal Article
Publication date: 2018-10-23
scimago Q1
wos Q1
SJR: 1.623
CiteScore: 12.5
Impact factor: 7.3
ISSN: 21680485
General Chemistry
General Chemical Engineering
Environmental Chemistry
Renewable Energy, Sustainability and the Environment
Abstract
Three geminal zwitterionic compounds are synthesized pursuing five parameters of green chemistry: atomic economy, environmental factor, mass intensity, mass reaction efficiency, and carbon efficiency; and evaluated as corrosion inhibitors for carbon steel (AISI–1018). The zwitterions are produced with variable length from amines (i.e., hydrocarbon chains), achieving mass reaction efficiencies higher than 80%, without the generation of wastes. The molecular structures are characterized using infrared spectroscopy and nuclear magnetic resonance. AISI–1018 steel coupons (blank corrosion) are used to test the corrosion inhibition of the geminal compounds at different concentrations (10, 25, 50, 75, and 100 ppm) in 1.0 M NaCl saturated with CO2 (pH = 3.5 and 70 °C). Electrochemical characterization is conducted using the open circuit potential (OCP) method, and polarization curves (±320 mV vs OCP) to determine the optimum concentrations in which the inhibitors decrease the corrosion rate of the steel. The corr...
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Juárez E. G. et al. Inhibition of CO2 Corrosion via Sustainable Geminal Zwitterionic Compounds: Effect of the Length of the Hydrocarbon Chain from Amines // ACS Sustainable Chemistry and Engineering. 2018. Vol. 6. No. 12. pp. 17230-17238.
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Juárez E. G., Mena Cervantes V. Y., Vazquez-Arenas J., Flores G. P., Hernández Altamirano R. Inhibition of CO2 Corrosion via Sustainable Geminal Zwitterionic Compounds: Effect of the Length of the Hydrocarbon Chain from Amines // ACS Sustainable Chemistry and Engineering. 2018. Vol. 6. No. 12. pp. 17230-17238.
Cite this
RIS
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TY - JOUR
DO - 10.1021/acssuschemeng.8b04619
UR - https://doi.org/10.1021/acssuschemeng.8b04619
TI - Inhibition of CO2 Corrosion via Sustainable Geminal Zwitterionic Compounds: Effect of the Length of the Hydrocarbon Chain from Amines
T2 - ACS Sustainable Chemistry and Engineering
AU - Juárez, Enrique Gómez
AU - Mena Cervantes, Violeta Y
AU - Vazquez-Arenas, Jorge
AU - Flores, Gabriel Pineda
AU - Hernández Altamirano, Raúl
PY - 2018
DA - 2018/10/23
PB - American Chemical Society (ACS)
SP - 17230-17238
IS - 12
VL - 6
SN - 2168-0485
ER -
Cite this
BibTex (up to 50 authors)
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@article{2018_Juárez,
author = {Enrique Gómez Juárez and Violeta Y Mena Cervantes and Jorge Vazquez-Arenas and Gabriel Pineda Flores and Raúl Hernández Altamirano},
title = {Inhibition of CO2 Corrosion via Sustainable Geminal Zwitterionic Compounds: Effect of the Length of the Hydrocarbon Chain from Amines},
journal = {ACS Sustainable Chemistry and Engineering},
year = {2018},
volume = {6},
publisher = {American Chemical Society (ACS)},
month = {oct},
url = {https://doi.org/10.1021/acssuschemeng.8b04619},
number = {12},
pages = {17230--17238},
doi = {10.1021/acssuschemeng.8b04619}
}
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MLA
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Juárez, Enrique Gómez, et al. “Inhibition of CO2 Corrosion via Sustainable Geminal Zwitterionic Compounds: Effect of the Length of the Hydrocarbon Chain from Amines.” ACS Sustainable Chemistry and Engineering, vol. 6, no. 12, Oct. 2018, pp. 17230-17238. https://doi.org/10.1021/acssuschemeng.8b04619.