OX-1 Metal–Organic Framework Nanosheets as Robust Hosts for Highly Active Catalytic Palladium Species
Kirill Titov
1
,
Dmitry B. Eremin
2
,
Alexey S Kashin
2
,
Roberto Boada
3
,
Barbara E Souza
1
,
Chris S Kelley
3
,
M.D Frogley
3
,
Gianfelice Cinque
3
,
D. Gianolio
3
,
G. Cibin
3
,
Svemir Rudić
4
,
Publication type: Journal Article
Publication date: 2019-02-20
scimago Q1
wos Q1
SJR: 1.623
CiteScore: 12.5
Impact factor: 7.3
ISSN: 21680485
General Chemistry
General Chemical Engineering
Environmental Chemistry
Renewable Energy, Sustainability and the Environment
Abstract
A catalytic system based on OX-1 metal–organic framework nanosheets is reported, incorporating catalytically active palladium (Pd) species. The Pd@OX-1 guest@host system is rapidly synthesized via a one-step single-pot supramolecular assembly, with the possibility of controlling the Pd loading. The structures of the resulting framework and of the active Pd species before and after catalytic reactions are studied in detail using a wide variety of techniques including synchrotron radiation infrared spectroscopy, inelastic neutron scattering, and X-ray absorption spectroscopy. Crystals of the resulting Pd@OX-1 composite material contain predominantly atomic and small cluster Pd species, which selectively reside on benzene rings of the benzenedicarboxylate (BDC) linkers. The composites are shown to efficiently catalyze the Suzuki coupling and Heck arylation reactions under a variety of conditions. Pd@OX-1 further shows potential to be recycled for at least five cycles of each reaction as well as an ability to...
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16
Total citations:
16
Citations from 2024:
2
(12%)
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GOST
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Titov K. et al. OX-1 Metal–Organic Framework Nanosheets as Robust Hosts for Highly Active Catalytic Palladium Species // ACS Sustainable Chemistry and Engineering. 2019. Vol. 7. No. 6. pp. 5875-5885.
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Titov K., Eremin D. B., Kashin A. S., Boada R., Souza B. E., Kelley C. S., Frogley M., Cinque G., Gianolio D., Cibin G., Rudić S., Ananikov V. P., Tan J. C. OX-1 Metal–Organic Framework Nanosheets as Robust Hosts for Highly Active Catalytic Palladium Species // ACS Sustainable Chemistry and Engineering. 2019. Vol. 7. No. 6. pp. 5875-5885.
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TY - JOUR
DO - 10.1021/acssuschemeng.8b05843
UR - https://doi.org/10.1021/acssuschemeng.8b05843
TI - OX-1 Metal–Organic Framework Nanosheets as Robust Hosts for Highly Active Catalytic Palladium Species
T2 - ACS Sustainable Chemistry and Engineering
AU - Titov, Kirill
AU - Eremin, Dmitry B.
AU - Kashin, Alexey S
AU - Boada, Roberto
AU - Souza, Barbara E
AU - Kelley, Chris S
AU - Frogley, M.D
AU - Cinque, Gianfelice
AU - Gianolio, D.
AU - Cibin, G.
AU - Rudić, Svemir
AU - Ananikov, Valentine P.
AU - Tan, Jin Chong
PY - 2019
DA - 2019/02/20
PB - American Chemical Society (ACS)
SP - 5875-5885
IS - 6
VL - 7
SN - 2168-0485
ER -
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BibTex (up to 50 authors)
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@article{2019_Titov,
author = {Kirill Titov and Dmitry B. Eremin and Alexey S Kashin and Roberto Boada and Barbara E Souza and Chris S Kelley and M.D Frogley and Gianfelice Cinque and D. Gianolio and G. Cibin and Svemir Rudić and Valentine P. Ananikov and Jin Chong Tan},
title = {OX-1 Metal–Organic Framework Nanosheets as Robust Hosts for Highly Active Catalytic Palladium Species},
journal = {ACS Sustainable Chemistry and Engineering},
year = {2019},
volume = {7},
publisher = {American Chemical Society (ACS)},
month = {feb},
url = {https://doi.org/10.1021/acssuschemeng.8b05843},
number = {6},
pages = {5875--5885},
doi = {10.1021/acssuschemeng.8b05843}
}
Cite this
MLA
Copy
Titov, Kirill, et al. “OX-1 Metal–Organic Framework Nanosheets as Robust Hosts for Highly Active Catalytic Palladium Species.” ACS Sustainable Chemistry and Engineering, vol. 7, no. 6, Feb. 2019, pp. 5875-5885. https://doi.org/10.1021/acssuschemeng.8b05843.