Accounts of Chemical Research

, том 37 , издание 8 , страницы 497-505

Ketone-Catalyzed Asymmetric Epoxidation Reactions

Тип публикации: Journal Article

Дата публикации: 2004-04-22

American Chemical Society (ACS)

Accounts of Chemical Research

scimago Q1

wos Q1

БС1

SJR: 5.433

CiteScore: 30.7

Impact factor: 17.7

ISSN: 00014842, 15204898

DOI: 10.1021/ar030065h

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PubMed ID: 15311948

General Chemistry

General Medicine

Краткое описание

This Account summarizes our efforts in developing organic ketone catalysts for enantioselective and diastereoselective epoxidation of olefins. We have developed an efficient and general protocol for epoxidation of olefins using dioxiranes generated in situ from activated ketones and Oxone (2KHSO5.KHSO4.K2SO4) in a homogeneous aqueous solvent system. We have also developed chiral ketone catalysts for highly enantioselective epoxidation of unfunctionalized trans-olefins and trisubstituted olefins. Excellent diastereoselectivities have been achieved for epoxidation of substituted cyclohexenes with ketone catalysts.

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Yang D. Ketone-Catalyzed Asymmetric Epoxidation Reactions // Accounts of Chemical Research. 2004. Vol. 37. No. 8. pp. 497-505.

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Yang D. Ketone-Catalyzed Asymmetric Epoxidation Reactions // Accounts of Chemical Research. 2004. Vol. 37. No. 8. pp. 497-505.

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TY - JOUR

DO - 10.1021/ar030065h

UR - https://doi.org/10.1021/ar030065h

TI - Ketone-Catalyzed Asymmetric Epoxidation Reactions

T2 - Accounts of Chemical Research

AU - Yang, Dan

PY - 2004

DA - 2004/04/22

PB - American Chemical Society (ACS)

SP - 497-505

IS - 8

VL - 37

PMID - 15311948

SN - 0001-4842

SN - 1520-4898

ER -

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@article{2004_Yang,

author = {Dan Yang},

title = {Ketone-Catalyzed Asymmetric Epoxidation Reactions},

journal = {Accounts of Chemical Research},

year = {2004},

volume = {37},

publisher = {American Chemical Society (ACS)},

month = {apr},

url = {https://doi.org/10.1021/ar030065h},

number = {8},

pages = {497--505},

doi = {10.1021/ar030065h}

}

MLA

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MLA Скопировать

Yang, Dan. “Ketone-Catalyzed Asymmetric Epoxidation Reactions.” Accounts of Chemical Research, vol. 37, no. 8, Apr. 2004, pp. 497-505. https://doi.org/10.1021/ar030065h.

Издатель

American Chemical Society (ACS)

Журнал

Accounts of Chemical Research

scimago Q1

wos Q1

БС1

SJR

5.433

CiteScore

30.7

Impact factor

17.7

ISSN

00014842 (Print)

15204898 (Electronic)