Do New Century Catalysts Unravel the Mechanism of Stereocontrol of Old Ziegler−Natta Catalysts?
Publication type: Journal Article
Publication date: 2004-03-25
scimago Q1
wos Q1
SJR: 5.433
CiteScore: 30.7
Impact factor: 17.7
ISSN: 00014842, 15204898
PubMed ID:
15096060
General Chemistry
General Medicine
Abstract
Stereoselective polymerization of 1-alkenes was discovered 50 years ago. However, a detailed knowledge of the traditional and industrially used Ziegler-Natta catalytic systems is still missing. Recently, well-defined homogeneous and octahedral complexes that polymerize propene to polypropylenes with microstructures extremely similar to those of polymers produced with the traditional catalysts were discovered. These catalysts offer the exciting opportunity to achieve insights into the mechanism of stereocontrol operative with the traditional catalytic systems.
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Total citations:
233
Citations from 2025:
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(2.15%)
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GOST
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Corradini P., Guerra G., Cavallo L. M. Do New Century Catalysts Unravel the Mechanism of Stereocontrol of Old Ziegler−Natta Catalysts? // Accounts of Chemical Research. 2004. Vol. 37. No. 4. pp. 231-241.
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Corradini P., Guerra G., Cavallo L. M. Do New Century Catalysts Unravel the Mechanism of Stereocontrol of Old Ziegler−Natta Catalysts? // Accounts of Chemical Research. 2004. Vol. 37. No. 4. pp. 231-241.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/ar030165n
UR - https://doi.org/10.1021/ar030165n
TI - Do New Century Catalysts Unravel the Mechanism of Stereocontrol of Old Ziegler−Natta Catalysts?
T2 - Accounts of Chemical Research
AU - Corradini, P
AU - Guerra, G.
AU - Cavallo, Luigi Maria
PY - 2004
DA - 2004/03/25
PB - American Chemical Society (ACS)
SP - 231-241
IS - 4
VL - 37
PMID - 15096060
SN - 0001-4842
SN - 1520-4898
ER -
Cite this
BibTex (up to 50 authors)
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@article{2004_Corradini,
author = {P Corradini and G. Guerra and Luigi Maria Cavallo},
title = {Do New Century Catalysts Unravel the Mechanism of Stereocontrol of Old Ziegler−Natta Catalysts?},
journal = {Accounts of Chemical Research},
year = {2004},
volume = {37},
publisher = {American Chemical Society (ACS)},
month = {mar},
url = {https://doi.org/10.1021/ar030165n},
number = {4},
pages = {231--241},
doi = {10.1021/ar030165n}
}
Cite this
MLA
Copy
Corradini, P., et al. “Do New Century Catalysts Unravel the Mechanism of Stereocontrol of Old Ziegler−Natta Catalysts?.” Accounts of Chemical Research, vol. 37, no. 4, Mar. 2004, pp. 231-241. https://doi.org/10.1021/ar030165n.