Relativistic effects on chemical properties
Тип публикации: Journal Article
Дата публикации: 1979-08-01
SCImago Q1
Tоп 10% SCImago
WOS Q1
БС1
SJR: 5.472
CiteScore: 31.2
Impact factor: 18
ISSN: 00014842, 15204898
General Chemistry
General Medicine
Краткое описание
Special or anomalous chemical effects are examined in relation to periodic-table trends, and the degree to which these are relativistic effects are determined. It is noted that the degree to which these relativistic effects and the introduction of 4f electrons (the usual textbook explanation of the anomalies) affect chemical behavior are of approx. equal magnitude. The anomalies that are discussed in light of relativistic effects are (1) the lanthanide contraction; (2) the inert pair effect; and (3) the unique properties of Au (as compared to Ag and Cu), of Hg (as compared to Cd and Zn), and of U/sup 6 +/, Np/sup 6 +/, and Pu/sup 6 +/ (as compared to the corresponding lanthanides). 29 references are cited. (BLM)
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ГОСТ
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PITZER K. S. Relativistic effects on chemical properties // Accounts of Chemical Research. 1979. Vol. 12. No. 8. pp. 271-276.
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PITZER K. S. Relativistic effects on chemical properties // Accounts of Chemical Research. 1979. Vol. 12. No. 8. pp. 271-276.
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TY - JOUR
DO - 10.1021/ar50140a001
UR - https://doi.org/10.1021/ar50140a001
TI - Relativistic effects on chemical properties
T2 - Accounts of Chemical Research
AU - PITZER, KENNETH S.
PY - 1979
DA - 1979/08/01
PB - American Chemical Society (ACS)
SP - 271-276
IS - 8
VL - 12
SN - 0001-4842
SN - 1520-4898
ER -
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BibTex (до 50 авторов)
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@article{1979_PITZER,
author = {KENNETH S. PITZER},
title = {Relativistic effects on chemical properties},
journal = {Accounts of Chemical Research},
year = {1979},
volume = {12},
publisher = {American Chemical Society (ACS)},
month = {aug},
url = {https://doi.org/10.1021/ar50140a001},
number = {8},
pages = {271--276},
doi = {10.1021/ar50140a001}
}
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MLA
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PITZER, KENNETH S.. “Relativistic effects on chemical properties.” Accounts of Chemical Research, vol. 12, no. 8, Aug. 1979, pp. 271-276. https://doi.org/10.1021/ar50140a001.
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