Excited-State Proton Transfer: From Constrained Systems to “Super” Photoacids to Superfast Proton Transfer†
Publication type: Journal Article
Publication date: 2001-11-27
scimago Q1
wos Q1
SJR: 5.433
CiteScore: 30.7
Impact factor: 17.7
ISSN: 00014842, 15204898
PubMed ID:
11790085
General Chemistry
General Medicine
Abstract
We have used knowledge of the electronic structure of excited states of acids to design molecules that exhibit enhanced excited-state acidity. Such "super" photoacids are the strongest reversible photoacids known and allow the time evolution of proton transfer to be examined in a wide array of organic solvents. This includes breaking/formation of the hydrogen bonds in hundreds of femtoseconds, solvent reorientation and relaxation in picoseconds, proton dissociation, and, finally, diffusion and geminate recombination of the dissociated proton, observed in nanoseconds.
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751
Total citations:
751
Citations from 2025:
28
(3.73%)
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Tolbert L. M., Solntsev K. M. Excited-State Proton Transfer: From Constrained Systems to “Super” Photoacids to Superfast Proton Transfer† // Accounts of Chemical Research. 2001. Vol. 35. No. 1. pp. 19-27.
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Tolbert L. M., Solntsev K. M. Excited-State Proton Transfer: From Constrained Systems to “Super” Photoacids to Superfast Proton Transfer† // Accounts of Chemical Research. 2001. Vol. 35. No. 1. pp. 19-27.
Cite this
RIS
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TY - JOUR
DO - 10.1021/ar990109f
UR - https://doi.org/10.1021/ar990109f
TI - Excited-State Proton Transfer: From Constrained Systems to “Super” Photoacids to Superfast Proton Transfer†
T2 - Accounts of Chemical Research
AU - Tolbert, Laren M.
AU - Solntsev, Kyril M
PY - 2001
DA - 2001/11/27
PB - American Chemical Society (ACS)
SP - 19-27
IS - 1
VL - 35
PMID - 11790085
SN - 0001-4842
SN - 1520-4898
ER -
Cite this
BibTex (up to 50 authors)
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@article{2001_Tolbert,
author = {Laren M. Tolbert and Kyril M Solntsev},
title = {Excited-State Proton Transfer: From Constrained Systems to “Super” Photoacids to Superfast Proton Transfer†},
journal = {Accounts of Chemical Research},
year = {2001},
volume = {35},
publisher = {American Chemical Society (ACS)},
month = {nov},
url = {https://doi.org/10.1021/ar990109f},
number = {1},
pages = {19--27},
doi = {10.1021/ar990109f}
}
Cite this
MLA
Copy
Tolbert, Laren M., and Kyril M Solntsev. “Excited-State Proton Transfer: From Constrained Systems to “Super” Photoacids to Superfast Proton Transfer†.” Accounts of Chemical Research, vol. 35, no. 1, Nov. 2001, pp. 19-27. https://doi.org/10.1021/ar990109f.