Role of Multicentered Bonding in Controlling Magnetic Interactions in π-Stacked Bis-dithiazolyl Radical
Тип публикации: Journal Article
Дата публикации: 2011-06-01
SCImago Q2
WOS Q1
БС1
SJR: 0.62
CiteScore: 5.5
Impact factor: 3.6
ISSN: 15287483, 15287505
General Chemistry
Condensed Matter Physics
General Materials Science
Краткое описание
Crystal structure analyses and quantum chemical calculations on the bis-dithiazolyl radical (BTA·) reveal that this neutral radical forms stable π-stacked multicentered bonding in the dimer. The overall macroscopic magnetic behavior of the crystal of this molecule is controlled by the strength of this interaction. Increasing the intermolecular distance between BTA· leads to an antiferromagnetic → ferromagnetic crossover in this class of organic conductors. BTA· along with the phenalenyl radical (PHEN·) represents a new class of neutral pure aromatic organic radicals where such multicentered bonding exists.
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Jose D., Datta A. Role of Multicentered Bonding in Controlling Magnetic Interactions in π-Stacked Bis-dithiazolyl Radical // Crystal Growth and Design. 2011. Vol. 11. No. 7. pp. 3137-3140.
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Jose D., Datta A. Role of Multicentered Bonding in Controlling Magnetic Interactions in π-Stacked Bis-dithiazolyl Radical // Crystal Growth and Design. 2011. Vol. 11. No. 7. pp. 3137-3140.
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TY - JOUR
DO - 10.1021/cg200396v
UR - https://doi.org/10.1021/cg200396v
TI - Role of Multicentered Bonding in Controlling Magnetic Interactions in π-Stacked Bis-dithiazolyl Radical
T2 - Crystal Growth and Design
AU - Jose, Deepthi
AU - Datta, Ayan
PY - 2011
DA - 2011/06/01
PB - American Chemical Society (ACS)
SP - 3137-3140
IS - 7
VL - 11
SN - 1528-7483
SN - 1528-7505
ER -
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@article{2011_Jose,
author = {Deepthi Jose and Ayan Datta},
title = {Role of Multicentered Bonding in Controlling Magnetic Interactions in π-Stacked Bis-dithiazolyl Radical},
journal = {Crystal Growth and Design},
year = {2011},
volume = {11},
publisher = {American Chemical Society (ACS)},
month = {jun},
url = {https://doi.org/10.1021/cg200396v},
number = {7},
pages = {3137--3140},
doi = {10.1021/cg200396v}
}
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MLA
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Jose, Deepthi, and Ayan Datta. “Role of Multicentered Bonding in Controlling Magnetic Interactions in π-Stacked Bis-dithiazolyl Radical.” Crystal Growth and Design, vol. 11, no. 7, Jun. 2011, pp. 3137-3140. https://doi.org/10.1021/cg200396v.
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