Role of Multicentered Bonding in Controlling Magnetic Interactions in π-Stacked Bis-dithiazolyl Radical
Publication type: Journal Article
Publication date: 2011-06-01
scimago Q2
wos Q1
SJR: 0.633
CiteScore: 5.6
Impact factor: 3.4
ISSN: 15287483, 15287505
General Chemistry
Condensed Matter Physics
General Materials Science
Abstract
Crystal structure analyses and quantum chemical calculations on the bis-dithiazolyl radical (BTA·) reveal that this neutral radical forms stable π-stacked multicentered bonding in the dimer. The overall macroscopic magnetic behavior of the crystal of this molecule is controlled by the strength of this interaction. Increasing the intermolecular distance between BTA· leads to an antiferromagnetic → ferromagnetic crossover in this class of organic conductors. BTA· along with the phenalenyl radical (PHEN·) represents a new class of neutral pure aromatic organic radicals where such multicentered bonding exists.
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Total citations:
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Citations from 2024:
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(4.26%)
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GOST
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Jose D., Datta A. Role of Multicentered Bonding in Controlling Magnetic Interactions in π-Stacked Bis-dithiazolyl Radical // Crystal Growth and Design. 2011. Vol. 11. No. 7. pp. 3137-3140.
GOST all authors (up to 50)
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Jose D., Datta A. Role of Multicentered Bonding in Controlling Magnetic Interactions in π-Stacked Bis-dithiazolyl Radical // Crystal Growth and Design. 2011. Vol. 11. No. 7. pp. 3137-3140.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/cg200396v
UR - https://doi.org/10.1021/cg200396v
TI - Role of Multicentered Bonding in Controlling Magnetic Interactions in π-Stacked Bis-dithiazolyl Radical
T2 - Crystal Growth and Design
AU - Jose, Deepthi
AU - Datta, Ayan
PY - 2011
DA - 2011/06/01
PB - American Chemical Society (ACS)
SP - 3137-3140
IS - 7
VL - 11
SN - 1528-7483
SN - 1528-7505
ER -
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BibTex (up to 50 authors)
Copy
@article{2011_Jose,
author = {Deepthi Jose and Ayan Datta},
title = {Role of Multicentered Bonding in Controlling Magnetic Interactions in π-Stacked Bis-dithiazolyl Radical},
journal = {Crystal Growth and Design},
year = {2011},
volume = {11},
publisher = {American Chemical Society (ACS)},
month = {jun},
url = {https://doi.org/10.1021/cg200396v},
number = {7},
pages = {3137--3140},
doi = {10.1021/cg200396v}
}
Cite this
MLA
Copy
Jose, Deepthi, and Ayan Datta. “Role of Multicentered Bonding in Controlling Magnetic Interactions in π-Stacked Bis-dithiazolyl Radical.” Crystal Growth and Design, vol. 11, no. 7, Jun. 2011, pp. 3137-3140. https://doi.org/10.1021/cg200396v.