volume 14 issue 11 pages 5976-5984

Supramolecular assembly of organophosphonate diesters using paddle-wheel complexes: First examples in porphyrin series

Publication typeJournal Article
Publication date2014-10-27
scimago Q2
wos Q1
SJR0.633
CiteScore5.6
Impact factor3.4
ISSN15287483, 15287505
General Chemistry
Condensed Matter Physics
General Materials Science
Abstract
The reactions of dicopper tetrapivalate complex Cu2(μ-OOC-t-Bu)4(NCMe)2 (1) with triphenylphosphine oxide and diethyl phosphite allow paddle-wheel (PW) copper(II) complexes with phosphorus-containing axial ligands (2, 3) to be obtained. When meso-bis(diethoxyphosphoryl)porphyrins 4M were employed in this ligand exchange reaction, a series of one-dimensional (1D) homo- and heterometallic coordination polymers 5M composed of PW subunits and organophosphonate diesters were prepared and characterized by means of single crystal X-ray analysis. Planar porphyrinate 4Pd and nonplanar metalloporphyrinates 4Cu and 4Ni proved to be appropriate molecular structural blocks for assembly of coordination polymers. The structural parameters of the tetrapyrrolic macrocycles incorporated into the polymer chain are determined by the nature of the metal center of the porphyrin moiety. While the geometry of palladium(II) and nickel(II) porphyrinates 4Pd and 4Ni does not change significantly in the polymer chain, saddle-shaped ...
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Uvarova M. A. et al. Supramolecular assembly of organophosphonate diesters using paddle-wheel complexes: First examples in porphyrin series // Crystal Growth and Design. 2014. Vol. 14. No. 11. pp. 5976-5984.
GOST all authors (up to 50) Copy
Uvarova M. A., Sinelshchikova A., Sinelshchikova A. A., Golubnichaya M. A., Nefedov S. E., Enakieva Y. Y., Gorbunova Y. G., Tsivadze A., Tsivadze A. Y., Stern C., Bessmertnykh-Lemeune A., Guilard R. Supramolecular assembly of organophosphonate diesters using paddle-wheel complexes: First examples in porphyrin series // Crystal Growth and Design. 2014. Vol. 14. No. 11. pp. 5976-5984.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1021/cg501157e
UR - https://pubs.acs.org/doi/10.1021/cg501157e
TI - Supramolecular assembly of organophosphonate diesters using paddle-wheel complexes: First examples in porphyrin series
T2 - Crystal Growth and Design
AU - Uvarova, Marina A
AU - Sinelshchikova, Anna
AU - Sinelshchikova, Anna A
AU - Golubnichaya, Margarita A
AU - Nefedov, Sergey E.
AU - Enakieva, Yulia Yu.
AU - Gorbunova, Yulia G.
AU - Tsivadze, Aslan
AU - Tsivadze, Aslan Yu.
AU - Stern, Christine
AU - Bessmertnykh-Lemeune, Alla
AU - Guilard, Roger
PY - 2014
DA - 2014/10/27
PB - American Chemical Society (ACS)
SP - 5976-5984
IS - 11
VL - 14
SN - 1528-7483
SN - 1528-7505
ER -
BibTex |
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BibTex (up to 50 authors) Copy
@article{2014_Uvarova,
author = {Marina A Uvarova and Anna Sinelshchikova and Anna A Sinelshchikova and Margarita A Golubnichaya and Sergey E. Nefedov and Yulia Yu. Enakieva and Yulia G. Gorbunova and Aslan Tsivadze and Aslan Yu. Tsivadze and Christine Stern and Alla Bessmertnykh-Lemeune and Roger Guilard},
title = {Supramolecular assembly of organophosphonate diesters using paddle-wheel complexes: First examples in porphyrin series},
journal = {Crystal Growth and Design},
year = {2014},
volume = {14},
publisher = {American Chemical Society (ACS)},
month = {oct},
url = {https://pubs.acs.org/doi/10.1021/cg501157e},
number = {11},
pages = {5976--5984},
doi = {10.1021/cg501157e}
}
MLA
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MLA Copy
Uvarova, Marina A., et al. “Supramolecular assembly of organophosphonate diesters using paddle-wheel complexes: First examples in porphyrin series.” Crystal Growth and Design, vol. 14, no. 11, Oct. 2014, pp. 5976-5984. https://pubs.acs.org/doi/10.1021/cg501157e.