Chemical Reviews, volume 109, issue 5, pages 2119-2183
C−F Bond Activation in Organic Synthesis
Publication type: Journal Article
Publication date: 2009-03-30
Journal:
Chemical Reviews
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 62.1
ISSN: 00092665, 15206890
General Chemistry
Abstract
Fluorine has received great attention in all fields of science. “Small atom with a big ego” was the title of the Symposium at the ACS meeting in San Francisco in 2000, where a number of the current scientific and industrial aspects of fluorine chemistry made possible by the small size and high electronegativity of the atom were discussed. This small atom has provided mankind with significant benefits in special products such as poly(tetrafluroethylene) (PTFE), freon, fluoro-liquid crystals, optical fiber, pharmaceutical and agrochemical compounds, and so on, all of which have their own unique properties that are otherwise difficult to obtain.1 For instance, at present, up to 30% of agrochemicals and 10% of pharmaceuticals currently used contain fluorine atoms. Therefore, organic fluorine compounds have received a great deal of interest and attention from the scientists involved in diverse fields of science and technology. Now, not only C-F bond formation but also selective C-F bond activation have become current subjects of active investigation from the viewpoint of effective synthesis of fluoroorganic compounds. The former is highlighted by designing a sophisticated fluorinating reagent for regioand stereocontrolled fluorination and developing versatile multifunctional and easily prepared building blocks. C-F bond formation has been treated extensively in several reviews2 and books.3 The latter is a subject that has been less explored but would be promising for selective defluorination of aliphatic fluorides, cross-coupling with aryl fluorides, and * To whom correspondence should be addressed. Phone: 81-78-803-5799. Fax: 81-78-803-5799. E-mail: amii@kobe-u.ac.jp and uneyamak@cc.okayamau.ac.jp. † Kobe University. ‡ Okayama University. Chem. Rev. 2009, 109, 2119–2183 2119
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Citations by publishers
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- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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TY - JOUR
DO - 10.1021/cr800388c
UR - https://doi.org/10.1021/cr800388c
TI - C−F Bond Activation in Organic Synthesis
T2 - Chemical Reviews
AU - UNEYAMA, Kenji
AU - Amii, Hideki
PY - 2009
DA - 2009/03/30 00:00:00
PB - American Chemical Society (ACS)
SP - 2119-2183
IS - 5
VL - 109
SN - 0009-2665
SN - 1520-6890
ER -
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@article{2009_Amii,
author = {Kenji UNEYAMA and Hideki Amii},
title = {C−F Bond Activation in Organic Synthesis},
journal = {Chemical Reviews},
year = {2009},
volume = {109},
publisher = {American Chemical Society (ACS)},
month = {mar},
url = {https://doi.org/10.1021/cr800388c},
number = {5},
pages = {2119--2183},
doi = {10.1021/cr800388c}
}
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Amii, Hideki, and Kenji UNEYAMA. “C−F Bond Activation in Organic Synthesis.” Chemical Reviews, vol. 109, no. 5, Mar. 2009, pp. 2119-2183. https://doi.org/10.1021/cr800388c.