[Ni(PMe2NPh2)2](BF4)2 as an Electrocatalyst for H2 Production
Тип публикации: Journal Article
Дата публикации: 2012-03-30
scimago Q1
wos Q1
БС1
SJR: 3.847
CiteScore: 20.8
Impact factor: 13.1
ISSN: 21555435
General Chemistry
Catalysis
Краткое описание
A nickel(II) bis(diphosphine) complex, [Ni(PMe2NPh2)2](BF4)2 (PMe2NPh2 = 1,5-diphenyl-3,7-dimethyl-1,5-diaza-3,7-diphosphacyclooctane), has been synthesized and characterized. This complex, which contains pendant amines in the diphosphine ligand, is an electrocatalyst for hydrogen production by proton reduction. Using [(DMF)H]OTf as the acid, a turnover frequency of 1,540 s–1 was obtained with no added water, and a turnover frequency of 6,700 s–1 was found with 1.0 M water added. Thermochemical studies show that the hydride donor ability of [HNi(PMe2NPh2)2](BF4) is ΔG°H– = 54.0 kcal/mol, and we estimate a driving force for H2 elimination of 13.8 kcal/mol. [Ni(PMe2NPh2)2](BF4)2 is the fastest H2 production catalyst in the [Ni(PR2NR′2)2](BF4)2 family of complexes.
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ГОСТ
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Wiese S. et al. [Ni(PMe2NPh2)2](BF4)2 as an Electrocatalyst for H2 Production // ACS Catalysis. 2012. Vol. 2. No. 5. pp. 720-727.
ГОСТ со всеми авторами (до 50)
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Wiese S., Kilgore U. J., Dubois D. L., Bullock R. [Ni(PMe2NPh2)2](BF4)2 as an Electrocatalyst for H2 Production // ACS Catalysis. 2012. Vol. 2. No. 5. pp. 720-727.
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RIS
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TY - JOUR
DO - 10.1021/cs300019h
UR - https://doi.org/10.1021/cs300019h
TI - [Ni(PMe2NPh2)2](BF4)2 as an Electrocatalyst for H2 Production
T2 - ACS Catalysis
AU - Wiese, Stefan
AU - Kilgore, Uriah J.
AU - Dubois, Daniel L
AU - Bullock, Ross
PY - 2012
DA - 2012/03/30
PB - American Chemical Society (ACS)
SP - 720-727
IS - 5
VL - 2
SN - 2155-5435
ER -
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BibTex (до 50 авторов)
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@article{2012_Wiese,
author = {Stefan Wiese and Uriah J. Kilgore and Daniel L Dubois and Ross Bullock},
title = {[Ni(PMe2NPh2)2](BF4)2 as an Electrocatalyst for H2 Production},
journal = {ACS Catalysis},
year = {2012},
volume = {2},
publisher = {American Chemical Society (ACS)},
month = {mar},
url = {https://doi.org/10.1021/cs300019h},
number = {5},
pages = {720--727},
doi = {10.1021/cs300019h}
}
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MLA
Скопировать
Wiese, Stefan, et al. “[Ni(PMe2NPh2)2](BF4)2 as an Electrocatalyst for H2 Production.” ACS Catalysis, vol. 2, no. 5, Mar. 2012, pp. 720-727. https://doi.org/10.1021/cs300019h.