ACS Catalysis, volume 5, issue 3, pages 1581-1588
Adding Value to Power Station Captured CO2: Tolerant Zn and Mg Homogeneous Catalysts for Polycarbonate Polyol Production
Publication type: Journal Article
Publication date: 2015-02-10
General Chemistry
Catalysis
Abstract
Using captured waste carbon dioxide (CCU) as a chemical reagent is an attractive means to add value to carbon capture and storage (CCS) and is a high-priority target for manufacturing. One promising route is to copolymerize carbon dioxide and epoxides, to prepare aliphatic polycarbonates. In this study, three homogeneous dinuclear Zn and Mg catalysts, previously reported by our group (see Kember, M. R.; Knight, P. D.; Reung, P. T. R.; Williams, C. K Angew. Chem., Int. Ed. 2009, 48, 931–933 and Kember, M. R.; Williams, C. K. J. Am. Chem. Soc. 2012, 134, 15676–15679) have been investigated using captured and contaminated carbon dioxide, with cyclohexene oxide, to produce polymers. Carbon dioxide captured from the carbon capture demonstrator plant at Ferrybridge Power Station, U.K., is applied for the efficient production of poly(cyclohexylene carbonate). Remarkably, the dinuclear Zn and Mg catalysts display nearly equivalent turnover numbers (TON) and turnover frequencies (TOF) using captured CO2 versus tho...
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Chapman A. M. et al. Adding Value to Power Station Captured CO2: Tolerant Zn and Mg Homogeneous Catalysts for Polycarbonate Polyol Production // ACS Catalysis. 2015. Vol. 5. No. 3. pp. 1581-1588.
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Chapman A. M., Keyworth C., Kember M. R., Lennox A. J. J., Williams C. Adding Value to Power Station Captured CO2: Tolerant Zn and Mg Homogeneous Catalysts for Polycarbonate Polyol Production // ACS Catalysis. 2015. Vol. 5. No. 3. pp. 1581-1588.
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TY - JOUR
DO - 10.1021/cs501798s
UR - https://doi.org/10.1021/cs501798s
TI - Adding Value to Power Station Captured CO2: Tolerant Zn and Mg Homogeneous Catalysts for Polycarbonate Polyol Production
T2 - ACS Catalysis
AU - Chapman, A M.
AU - Keyworth, C
AU - Kember, M R
AU - Lennox, Alastair J J
AU - Williams, Charlotte
PY - 2015
DA - 2015/02/10
PB - American Chemical Society (ACS)
SP - 1581-1588
IS - 3
VL - 5
SN - 2155-5435
ER -
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@article{2015_Chapman,
author = {A M. Chapman and C Keyworth and M R Kember and Alastair J J Lennox and Charlotte Williams},
title = {Adding Value to Power Station Captured CO2: Tolerant Zn and Mg Homogeneous Catalysts for Polycarbonate Polyol Production},
journal = {ACS Catalysis},
year = {2015},
volume = {5},
publisher = {American Chemical Society (ACS)},
month = {feb},
url = {https://doi.org/10.1021/cs501798s},
number = {3},
pages = {1581--1588},
doi = {10.1021/cs501798s}
}
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MLA
Copy
Chapman, A. M., et al. “Adding Value to Power Station Captured CO2: Tolerant Zn and Mg Homogeneous Catalysts for Polycarbonate Polyol Production.” ACS Catalysis, vol. 5, no. 3, Feb. 2015, pp. 1581-1588. https://doi.org/10.1021/cs501798s.