Paramagnetic Susceptibility by NMR: The "Solvent Correction" Removed for Large Paramagnetic Molecules
Тип публикации: Journal Article
Дата публикации: 1997-07-01
SCImago Q2
WOS Q1
БС1
SJR: 0.626
CiteScore: 5
Impact factor: 3
ISSN: 00219584, 19381328
General Chemistry
Education
Краткое описание
For large paramagnetic molecules in solution, the paramagnetic and diamagnetic contributions to the magnetic susceptibility are comparable and may be determined by NMR (Evans' method) in the same conditions (concentration, temperature, solvent). Theoretical considerations show that the solvent correction similarly affects both measurements and cancels in the combined equations calculating the magnetic susceptibilities and the magnetic moments. These simplified equations have been successfully applied for the determination of the magnetism of self-assembled heterodinuclear 3d-4f supramolecular complexes in acetonitrile.
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ГОСТ
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Piguet C. Paramagnetic Susceptibility by NMR: The "Solvent Correction" Removed for Large Paramagnetic Molecules // Journal of Chemical Education. 1997. Vol. 74. No. 7. p. 815.
ГОСТ со всеми авторами (до 50)
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Piguet C. Paramagnetic Susceptibility by NMR: The "Solvent Correction" Removed for Large Paramagnetic Molecules // Journal of Chemical Education. 1997. Vol. 74. No. 7. p. 815.
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RIS
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TY - JOUR
DO - 10.1021/ed074p815
UR - https://doi.org/10.1021/ed074p815
TI - Paramagnetic Susceptibility by NMR: The "Solvent Correction" Removed for Large Paramagnetic Molecules
T2 - Journal of Chemical Education
AU - Piguet, C.
PY - 1997
DA - 1997/07/01
PB - American Chemical Society (ACS)
SP - 815
IS - 7
VL - 74
SN - 0021-9584
SN - 1938-1328
ER -
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BibTex (до 50 авторов)
Скопировать
@article{1997_Piguet,
author = {C. Piguet},
title = {Paramagnetic Susceptibility by NMR: The "Solvent Correction" Removed for Large Paramagnetic Molecules},
journal = {Journal of Chemical Education},
year = {1997},
volume = {74},
publisher = {American Chemical Society (ACS)},
month = {jul},
url = {https://doi.org/10.1021/ed074p815},
number = {7},
pages = {815},
doi = {10.1021/ed074p815}
}
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MLA
Скопировать
Piguet, C.. “Paramagnetic Susceptibility by NMR: The "Solvent Correction" Removed for Large Paramagnetic Molecules.” Journal of Chemical Education, vol. 74, no. 7, Jul. 1997, p. 815. https://doi.org/10.1021/ed074p815.
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