Effect of arene substituents and temperature on the arene replacement reactions of [(.eta.5-C5H5)Fe(.eta.6-arene)]+ and [(.eta.5-C5H5)Ru(.eta.6-arene)]+
Тип публикации: Journal Article
Дата публикации: 1984-08-01
scimago Q1
wos Q1
БС1
SJR: 0.928
CiteScore: 7.6
Impact factor: 4.7
ISSN: 00201669, 1520510X
Inorganic Chemistry
Physical and Theoretical Chemistry
Краткое описание
Results are reported for investigations to identify the photoactive excited states, delineate substitutent effects, and determine the temperature dependence of the quantum yield for Fe(II)- and Ru(II)-substituted arene complexes. These studies indicate metal-arene bond cleavage for complexes of both metals is nearly complete in the reactive excited state, but nucleophilic interactions of the medium in the transition state ultimately control the quantum yield of arene release for a given complex.
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Mcnair A. M., Schrenk J. L., Mann K. R. Effect of arene substituents and temperature on the arene replacement reactions of [(.eta.5-C5H5)Fe(.eta.6-arene)]+ and [(.eta.5-C5H5)Ru(.eta.6-arene)]+ // Inorganic Chemistry. 1984. Vol. 23. No. 17. pp. 2633-2640.
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Mcnair A. M., Schrenk J. L., Mann K. R. Effect of arene substituents and temperature on the arene replacement reactions of [(.eta.5-C5H5)Fe(.eta.6-arene)]+ and [(.eta.5-C5H5)Ru(.eta.6-arene)]+ // Inorganic Chemistry. 1984. Vol. 23. No. 17. pp. 2633-2640.
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TY - JOUR
DO - 10.1021/ic00185a018
UR - https://doi.org/10.1021/ic00185a018
TI - Effect of arene substituents and temperature on the arene replacement reactions of [(.eta.5-C5H5)Fe(.eta.6-arene)]+ and [(.eta.5-C5H5)Ru(.eta.6-arene)]+
T2 - Inorganic Chemistry
AU - Mcnair, Amy M
AU - Schrenk, Janet L
AU - Mann, Kent R.
PY - 1984
DA - 1984/08/01
PB - American Chemical Society (ACS)
SP - 2633-2640
IS - 17
VL - 23
SN - 0020-1669
SN - 1520-510X
ER -
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@article{1984_Mcnair,
author = {Amy M Mcnair and Janet L Schrenk and Kent R. Mann},
title = {Effect of arene substituents and temperature on the arene replacement reactions of [(.eta.5-C5H5)Fe(.eta.6-arene)]+ and [(.eta.5-C5H5)Ru(.eta.6-arene)]+},
journal = {Inorganic Chemistry},
year = {1984},
volume = {23},
publisher = {American Chemical Society (ACS)},
month = {aug},
url = {https://doi.org/10.1021/ic00185a018},
number = {17},
pages = {2633--2640},
doi = {10.1021/ic00185a018}
}
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MLA
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Mcnair, Amy M., et al. “Effect of arene substituents and temperature on the arene replacement reactions of [(.eta.5-C5H5)Fe(.eta.6-arene)]+ and [(.eta.5-C5H5)Ru(.eta.6-arene)]+.” Inorganic Chemistry, vol. 23, no. 17, Aug. 1984, pp. 2633-2640. https://doi.org/10.1021/ic00185a018.