Fluoride ion affinities of germanium tetrafluoride and boron trifluoride from thermodynamic and structural data for (SF3)2GeF6, ClO2GeF5, and ClO2BF4
Publication type: Journal Article
Publication date: 1984-09-01
scimago Q1
wos Q1
SJR: 0.958
CiteScore: 7.4
Impact factor: 4.7
ISSN: 00201669, 1520510X
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Results of studies to determine the fluoride ion affinity in GeF/sub 4/ and BF/sub 3/ are presented herein. Thermodynamic and structural data for (SF/sub 3/)/sub 2/GeF/sub 6/, ClO/sub 2/GeF/sub 2/, and ClO/sub 2/BF/sub 4/ are tabulated. The first fluoride ion affinity of GeF/sub 4/ was found to be 4-8kcal more energetic than that of BF/sub 3/. The packing volume of the BF/sub 4//sup -/ ion was found to be 16 +/- 2 A/sup 3/ which is less than the smaller GeF/sub 5//sup -/. It is noted that in small-cation structures, with close-packed ion arrangements, the lattice energy of fluoroborates can be approximately 5kcal mol/sup -1/ more favorable than for related fluorogermanates. Thus for this type of salts, the better fluoride acceptor ability of GeF/sub 4/ is largely offset by a poorer lattice energy, with the lattice difference decreasing as the cation becomes larger.
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219
Total citations:
219
Citations from 2025:
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(2.74%)
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GOST
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Mallouk T. et al. Fluoride ion affinities of germanium tetrafluoride and boron trifluoride from thermodynamic and structural data for (SF3)2GeF6, ClO2GeF5, and ClO2BF4 // Inorganic Chemistry. 1984. Vol. 23. No. 20. pp. 3167-3173.
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Rosenthal G. L., Mueller G., Brusasco R., Bartlett N. Fluoride ion affinities of germanium tetrafluoride and boron trifluoride from thermodynamic and structural data for (SF3)2GeF6, ClO2GeF5, and ClO2BF4 // Inorganic Chemistry. 1984. Vol. 23. No. 20. pp. 3167-3173.
Cite this
RIS
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TY - JOUR
DO - 10.1021/ic00188a028
UR - https://doi.org/10.1021/ic00188a028
TI - Fluoride ion affinities of germanium tetrafluoride and boron trifluoride from thermodynamic and structural data for (SF3)2GeF6, ClO2GeF5, and ClO2BF4
T2 - Inorganic Chemistry
AU - Rosenthal, Guy L
AU - Mueller, Gerhard
AU - Brusasco, Raymond
AU - Bartlett, Neil
PY - 1984
DA - 1984/09/01
PB - American Chemical Society (ACS)
SP - 3167-3173
IS - 20
VL - 23
SN - 0020-1669
SN - 1520-510X
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{1984_Mallouk,
author = {Guy L Rosenthal and Gerhard Mueller and Raymond Brusasco and Neil Bartlett},
title = {Fluoride ion affinities of germanium tetrafluoride and boron trifluoride from thermodynamic and structural data for (SF3)2GeF6, ClO2GeF5, and ClO2BF4},
journal = {Inorganic Chemistry},
year = {1984},
volume = {23},
publisher = {American Chemical Society (ACS)},
month = {sep},
url = {https://doi.org/10.1021/ic00188a028},
number = {20},
pages = {3167--3173},
doi = {10.1021/ic00188a028}
}
Cite this
MLA
Copy
Mallouk, T., et al. “Fluoride ion affinities of germanium tetrafluoride and boron trifluoride from thermodynamic and structural data for (SF3)2GeF6, ClO2GeF5, and ClO2BF4.” Inorganic Chemistry, vol. 23, no. 20, Sep. 1984, pp. 3167-3173. https://doi.org/10.1021/ic00188a028.