A Ligand-Field Analysis of the trensal (H3trensal = 2,2‘,2‘ ‘-Tris(salicylideneimino)triethylamine) Ligand. An Application of the Angular Overlap Model to Lanthanides
Тип публикации: Journal Article
Дата публикации: 2002-09-06
SCImago Q1
WOS Q1
БС1
SJR: 0.879
CiteScore: 7.5
Impact factor: 4.6
ISSN: 00201669, 1520510X
PubMed ID:
12354034
Inorganic Chemistry
Physical and Theoretical Chemistry
Краткое описание
The spectral and geometric trends of Ln(trensal) complexes (H3trensal = 2,2‘,2‘ ‘-tris(salicylideneimino)triethylamine) along the lanthanide series are analyzed. Low-temperature polarized absorption and luminescence spectra are reported for nine of the complexes with transitions suitable for analysis. Both the angular and radial geometry variations as a function of the lanthanide ion are quantified. The structural parameters are related to the trend in the ligand field found from an analysis of the f−f transitions. The ligand-field analysis is fitted globally across the whole series accounting for the contraction of the f orbitals as a function of atomic number. This study establishes the utility of describing the ligand field of f electrons within the one-electron operator approach of the angular overlap model.
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Flanagan B. M. et al. A Ligand-Field Analysis of the trensal (H3trensal = 2,2‘,2‘ ‘-Tris(salicylideneimino)triethylamine) Ligand. An Application of the Angular Overlap Model to Lanthanides // Inorganic Chemistry. 2002. Vol. 41. No. 20. pp. 5024-5033.
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Flanagan B. M., Bernhardt P. V., Krausz E., Lüthi S. R., Riley M. R. A Ligand-Field Analysis of the trensal (H3trensal = 2,2‘,2‘ ‘-Tris(salicylideneimino)triethylamine) Ligand. An Application of the Angular Overlap Model to Lanthanides // Inorganic Chemistry. 2002. Vol. 41. No. 20. pp. 5024-5033.
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TY - JOUR
DO - 10.1021/ic011276q
UR - https://doi.org/10.1021/ic011276q
TI - A Ligand-Field Analysis of the trensal (H3trensal = 2,2‘,2‘ ‘-Tris(salicylideneimino)triethylamine) Ligand. An Application of the Angular Overlap Model to Lanthanides
T2 - Inorganic Chemistry
AU - Flanagan, Bernadine M.
AU - Bernhardt, Paul V.
AU - Krausz, Elmars
AU - Lüthi, Stefan R.
AU - Riley, Mark R
PY - 2002
DA - 2002/09/06
PB - American Chemical Society (ACS)
SP - 5024-5033
IS - 20
VL - 41
PMID - 12354034
SN - 0020-1669
SN - 1520-510X
ER -
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@article{2002_Flanagan,
author = {Bernadine M. Flanagan and Paul V. Bernhardt and Elmars Krausz and Stefan R. Lüthi and Mark R Riley},
title = {A Ligand-Field Analysis of the trensal (H3trensal = 2,2‘,2‘ ‘-Tris(salicylideneimino)triethylamine) Ligand. An Application of the Angular Overlap Model to Lanthanides},
journal = {Inorganic Chemistry},
year = {2002},
volume = {41},
publisher = {American Chemical Society (ACS)},
month = {sep},
url = {https://doi.org/10.1021/ic011276q},
number = {20},
pages = {5024--5033},
doi = {10.1021/ic011276q}
}
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MLA
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Flanagan, Bernadine M., et al. “A Ligand-Field Analysis of the trensal (H3trensal = 2,2‘,2‘ ‘-Tris(salicylideneimino)triethylamine) Ligand. An Application of the Angular Overlap Model to Lanthanides.” Inorganic Chemistry, vol. 41, no. 20, Sep. 2002, pp. 5024-5033. https://doi.org/10.1021/ic011276q.
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