Structural and Mechanistic Investigations of the Oxidation of Dimethylplatinum(II) Complexes by Dioxygen
Publication type: Journal Article
Publication date: 2002-06-12
scimago Q1
wos Q1
SJR: 0.958
CiteScore: 7.4
Impact factor: 4.7
ISSN: 00201669, 1520510X
PubMed ID:
12099863
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
The oxidation of (tmeda)Pt(II)(CH(3))(2) (1, tmeda = N,N,N',N'-tetramethylethylenediamine) to (tmeda)Pt(IV)(OH)(OCH(3))(CH(3))(2) (3) by dioxygen in methanol proceeds via a two-step mechanism. The initial reaction between (tmeda)Pt(CH(3))(2) and dioxygen yields a hydroperoxoplatinum(IV) intermediate, (tmeda)Pt(OOH)(OCH(3))(CH(3))(2) (2), which reacts with a second equivalent of (tmeda)Pt(CH(3))(2) to afford the final product 3. Both 2 and 3 have been fully characterized, including X-ray crystallographic structure determinations. The effect of ligand variation on the oxidation of several dimethylplatinum(II) complexes by 2 as well as by dioxygen has been examined.
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135
Total citations:
135
Citations from 2025:
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(0.74%)
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Rostovtsev V. V. et al. Structural and Mechanistic Investigations of the Oxidation of Dimethylplatinum(II) Complexes by Dioxygen // Inorganic Chemistry. 2002. Vol. 41. No. 14. pp. 3608-3619.
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Rostovtsev V. V., Henling L. M., Labinger J., Bercaw J. E. Structural and Mechanistic Investigations of the Oxidation of Dimethylplatinum(II) Complexes by Dioxygen // Inorganic Chemistry. 2002. Vol. 41. No. 14. pp. 3608-3619.
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RIS
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TY - JOUR
DO - 10.1021/ic0112903
UR - https://doi.org/10.1021/ic0112903
TI - Structural and Mechanistic Investigations of the Oxidation of Dimethylplatinum(II) Complexes by Dioxygen
T2 - Inorganic Chemistry
AU - Rostovtsev, Vsevolod V
AU - Henling, Lawrence M.
AU - Labinger, Jay
AU - Bercaw, John E.
PY - 2002
DA - 2002/06/12
PB - American Chemical Society (ACS)
SP - 3608-3619
IS - 14
VL - 41
PMID - 12099863
SN - 0020-1669
SN - 1520-510X
ER -
Cite this
BibTex (up to 50 authors)
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@article{2002_Rostovtsev,
author = {Vsevolod V Rostovtsev and Lawrence M. Henling and Jay Labinger and John E. Bercaw},
title = {Structural and Mechanistic Investigations of the Oxidation of Dimethylplatinum(II) Complexes by Dioxygen},
journal = {Inorganic Chemistry},
year = {2002},
volume = {41},
publisher = {American Chemical Society (ACS)},
month = {jun},
url = {https://doi.org/10.1021/ic0112903},
number = {14},
pages = {3608--3619},
doi = {10.1021/ic0112903}
}
Cite this
MLA
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Rostovtsev, Vsevolod V., et al. “Structural and Mechanistic Investigations of the Oxidation of Dimethylplatinum(II) Complexes by Dioxygen.” Inorganic Chemistry, vol. 41, no. 14, Jun. 2002, pp. 3608-3619. https://doi.org/10.1021/ic0112903.