Synthesis and characterization of the first azastibatranes and azabismatranes
Тип публикации: Journal Article
Дата публикации: 2002-10-15
scimago Q1
wos Q1
БС1
SJR: 0.958
CiteScore: 7.4
Impact factor: 4.7
ISSN: 00201669, 1520510X
PubMed ID:
12425645
Inorganic Chemistry
Physical and Theoretical Chemistry
Краткое описание
Syntheses of title compounds, viz. N(CH2CH2NR)3E (1, E = Sb, R = Me; 4, E = Bi, R = Me; 6, E = Sb, R = SiMe3; 8, E = Bi, R = SiMe3), by the reaction of E(NAlk2)3 (3, E = Sb, Alk = Et; 5, E = Bi, Alk = Me) with N(CH2CH2NMeH)3 (2) or N(CH2CH2NSiMe3H)3 (7) are reported. The reactions of SbCl3 with N[CH2CH2N(Me)Li]3 or N[CH2CH2N(SiMe3)Li]3 and BiCl3 with N[CH2CH2N(SiMe3)Li]3 resulted in compounds 1, 6, and 8, respectively. Composition and structures of all novel compounds were established by 1H and 13C NMR spectroscopy and mass spectrometry. The X-ray structural study of 8 clearly indicated the presence of transannular interaction BiNdat in this compound, while 6 possesses a long Sb...Ndat distance. The structural data obtained from geometry optimizations on 6 and 8 reproduce experimental trends, i.e., a decrease in the E-Ndat distance from Sb to Bi. The values of electron density in E-Ndat critical point and the Laplacian of charge density for 8 indicate that a closed-shell interaction exists between the metal atom and Ndat atom.
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Shutov P. L. et al. Synthesis and characterization of the first azastibatranes and azabismatranes // Inorganic Chemistry. 2002. Vol. 41. No. 23. pp. 6147-6152.
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Shutov P. L., Karlov S. S., Harms K., Harms K., Tyurin D. A., Churakov A. V., Lorberth J., Zaitseva G. S. Synthesis and characterization of the first azastibatranes and azabismatranes // Inorganic Chemistry. 2002. Vol. 41. No. 23. pp. 6147-6152.
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TY - JOUR
DO - 10.1021/ic0257423
UR - https://pubs.acs.org/doi/10.1021/ic0257423
TI - Synthesis and characterization of the first azastibatranes and azabismatranes
T2 - Inorganic Chemistry
AU - Shutov, Pavel L
AU - Karlov, Sergey S.
AU - Harms, K.
AU - Harms, Klaus
AU - Tyurin, Daniil A
AU - Churakov, Andrei V.
AU - Lorberth, Jörg
AU - Zaitseva, Galina S.
PY - 2002
DA - 2002/10/15
PB - American Chemical Society (ACS)
SP - 6147-6152
IS - 23
VL - 41
PMID - 12425645
SN - 0020-1669
SN - 1520-510X
ER -
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@article{2002_Shutov,
author = {Pavel L Shutov and Sergey S. Karlov and K. Harms and Klaus Harms and Daniil A Tyurin and Andrei V. Churakov and Jörg Lorberth and Galina S. Zaitseva},
title = {Synthesis and characterization of the first azastibatranes and azabismatranes},
journal = {Inorganic Chemistry},
year = {2002},
volume = {41},
publisher = {American Chemical Society (ACS)},
month = {oct},
url = {https://pubs.acs.org/doi/10.1021/ic0257423},
number = {23},
pages = {6147--6152},
doi = {10.1021/ic0257423}
}
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Shutov, Pavel L., et al. “Synthesis and characterization of the first azastibatranes and azabismatranes.” Inorganic Chemistry, vol. 41, no. 23, Oct. 2002, pp. 6147-6152. https://pubs.acs.org/doi/10.1021/ic0257423.