Luminescent nido-Carborane−Diphosphine Anions [(PR2)2C2B9H10]- (R = Ph, iPr). Modification of Their Luminescence Properties upon Formation of Three-Coordinate Gold(I) Complexes
Тип публикации: Journal Article
Дата публикации: 2003-02-19
scimago Q1
wos Q1
БС1
SJR: 0.928
CiteScore: 7.6
Impact factor: 4.7
ISSN: 00201669, 1520510X
PubMed ID:
12639142
Inorganic Chemistry
Physical and Theoretical Chemistry
Краткое описание
The free nido-diphosphine anions [(PR(2))(2)C(2)B(9)H(10)](-) (R = Ph, (i)Pr) show luminescence properties whereas the closo-diphosphines [(PR(2))(2)C(2)B(10)H(10)] do not. Four families of three-coordinate complexes of stoichiometry [Au[(PR(2))(2)C(2)B(10)H(10)]L]OTf (L = tertiary phosphine) and [Au[(PR(2))(2)C(2)B(9)H(10)]L] have been studied in order to analyze the influence of the closo- or nido-nature of the diphosphine, the monophosphine coordinated to gold and the substituent at the diphosphine on the luminescence of the complexes. Only the nido-derivatives show luminescence. The maxima of the emissions are shifted to lower energies than those of the corresponding free nido-diphosphines. When the substituent at the diphosphine is phenyl, a new emission appears, which has been assigned as arising from a metal to ligand charge transfer [Au-->pi(L)] excited state.
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Crespo O. et al. Luminescent nido-Carborane−Diphosphine Anions [(PR2)2C2B9H10]- (R = Ph, iPr). Modification of Their Luminescence Properties upon Formation of Three-Coordinate Gold(I) Complexes // Inorganic Chemistry. 2003. Vol. 42. No. 6. pp. 2061-2068.
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Crespo O., Gimeno M. C., Jones P. G., Laguna A., López De Luzuriaga J. M., Monge M., Pérez J. L., Ramón M. A. Luminescent nido-Carborane−Diphosphine Anions [(PR2)2C2B9H10]- (R = Ph, iPr). Modification of Their Luminescence Properties upon Formation of Three-Coordinate Gold(I) Complexes // Inorganic Chemistry. 2003. Vol. 42. No. 6. pp. 2061-2068.
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TY - JOUR
DO - 10.1021/ic0259843
UR - https://doi.org/10.1021/ic0259843
TI - Luminescent nido-Carborane−Diphosphine Anions [(PR2)2C2B9H10]- (R = Ph, iPr). Modification of Their Luminescence Properties upon Formation of Three-Coordinate Gold(I) Complexes
T2 - Inorganic Chemistry
AU - Crespo, Olga
AU - Gimeno, M. Concepción
AU - Jones, Peter G.
AU - Laguna, Antonio
AU - López De Luzuriaga, Jose M
AU - Monge, Miguel
AU - Pérez, Juan L.
AU - Ramón, Miguel A
PY - 2003
DA - 2003/02/19
PB - American Chemical Society (ACS)
SP - 2061-2068
IS - 6
VL - 42
PMID - 12639142
SN - 0020-1669
SN - 1520-510X
ER -
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@article{2003_Crespo,
author = {Olga Crespo and M. Concepción Gimeno and Peter G. Jones and Antonio Laguna and Jose M López De Luzuriaga and Miguel Monge and Juan L. Pérez and Miguel A Ramón},
title = {Luminescent nido-Carborane−Diphosphine Anions [(PR2)2C2B9H10]- (R = Ph, iPr). Modification of Their Luminescence Properties upon Formation of Three-Coordinate Gold(I) Complexes},
journal = {Inorganic Chemistry},
year = {2003},
volume = {42},
publisher = {American Chemical Society (ACS)},
month = {feb},
url = {https://doi.org/10.1021/ic0259843},
number = {6},
pages = {2061--2068},
doi = {10.1021/ic0259843}
}
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MLA
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Crespo, Olga, et al. “Luminescent nido-Carborane−Diphosphine Anions [(PR2)2C2B9H10]- (R = Ph, iPr). Modification of Their Luminescence Properties upon Formation of Three-Coordinate Gold(I) Complexes.” Inorganic Chemistry, vol. 42, no. 6, Feb. 2003, pp. 2061-2068. https://doi.org/10.1021/ic0259843.