Inorganic Chemistry, volume 42, issue 8, pages 2714-2719
Rapid Solid-State Metathesis Routes to Aluminum Nitride
Publication type: Journal Article
Publication date: 2003-03-25
Journal:
Inorganic Chemistry
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 4.6
ISSN: 00201669, 1520510X
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Metathesis (exchange) reactions offer the possibility of controlling temperature through a judicious choice of precursors. Here, a reaction between AlCl(3) and Ca(3)N(2) is found to produce phase-pure aluminum nitride (AlN) in seconds. The CaCl(2) byproduct salt, whose formation drives this highly exothermic reaction, is simply washed away after reaction completion. SEM images demonstrate that the AlN product is a micron-sized powder, while TEM shows well-formed crystallites. Thermodynamic calculations indicate that a reaction temperature of 2208 K could be reached under adiabatic conditions. Using an in situ thermocouple and a stainless steel reactor vessel to hold the precursors, a reaction temperature of 1673 K is measured 0.8 s after initiation. Switching to a thermally insulating ceramic vessel produces a maximum reaction temperature of 2010 K because of the more nearly adiabatic conditions. The high reaction temperature appears to be critical to forming phase-pure AlN. Experiments with Li(3)N, instead of Ca(3)N(2), produce lower temperatures (1513 K), resulting in both Al and Al(2)O(3) impurities.
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Citations by publishers
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- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Janes R. A., Low M. A., Kaner R. Rapid Solid-State Metathesis Routes to Aluminum Nitride // Inorganic Chemistry. 2003. Vol. 42. No. 8. pp. 2714-2719.
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Janes R. A., Low M. A., Kaner R. Rapid Solid-State Metathesis Routes to Aluminum Nitride // Inorganic Chemistry. 2003. Vol. 42. No. 8. pp. 2714-2719.
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TY - JOUR
DO - 10.1021/ic026143z
UR - https://doi.org/10.1021/ic026143z
TI - Rapid Solid-State Metathesis Routes to Aluminum Nitride
T2 - Inorganic Chemistry
AU - Janes, Rebecca A
AU - Low, Madeleine A
AU - Kaner, Richard
PY - 2003
DA - 2003/03/25 00:00:00
PB - American Chemical Society (ACS)
SP - 2714-2719
IS - 8
VL - 42
SN - 0020-1669
SN - 1520-510X
ER -
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@article{2003_Janes,
author = {Rebecca A Janes and Madeleine A Low and Richard Kaner},
title = {Rapid Solid-State Metathesis Routes to Aluminum Nitride},
journal = {Inorganic Chemistry},
year = {2003},
volume = {42},
publisher = {American Chemical Society (ACS)},
month = {mar},
url = {https://doi.org/10.1021/ic026143z},
number = {8},
pages = {2714--2719},
doi = {10.1021/ic026143z}
}
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Janes, Rebecca A., et al. “Rapid Solid-State Metathesis Routes to Aluminum Nitride.” Inorganic Chemistry, vol. 42, no. 8, Mar. 2003, pp. 2714-2719. https://doi.org/10.1021/ic026143z.