[BDTA]2[Cu(mnt)2]: An Almost Perfect One-Dimensional Magnetic Material
Sarah S Staniland
1
,
Wataru FUJITA
1
,
Yoshikatsu Umezono
1
,
Kunio Awaga
1
,
Philip E. Camp
1
,
Stewart J. Clark
1
,
Publication type: Journal Article
Publication date: 2005-01-13
scimago Q1
wos Q1
SJR: 0.958
CiteScore: 7.4
Impact factor: 4.7
ISSN: 00201669, 1520510X
PubMed ID:
15679383
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
[BDTA]2[Cu(mnt)2] (BDTA = benzo-1,3,2-dithiazolyl, mnt = maleonitriledithiolate) was crystallized in the space group P with an inversion center on Cu giving a stacked structure with each metal complex anion sandwiched by two cations. Short intermolecular S...S contacts give rise to a one-dimensional chain lateral to the stacking axis. Variable-temperature magnetic susceptibility and EPR measurements indicate that the salt behaves as an ideal one-dimensional Heisenberg antiferromagnetic material from 2 K < or = T < or = 300 K, with a coupling constant of J/k(B) = 16-17 K; the very low temperature magnetic properties are in quantitative agreement with the predictions of quantum field theory. DFT calculations are consistent with the formation of a one-dimensional magnetic chain with interstack interactions mediated by the BDTA counterions.
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Staniland S. S. et al. [BDTA]2[Cu(mnt)2]: An Almost Perfect One-Dimensional Magnetic Material // Inorganic Chemistry. 2005. Vol. 44. No. 3. pp. 546-551.
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Staniland S. S., FUJITA W., Umezono Y., Awaga K., Camp P. E., Clark S. J., Robertson N. J. [BDTA]2[Cu(mnt)2]: An Almost Perfect One-Dimensional Magnetic Material // Inorganic Chemistry. 2005. Vol. 44. No. 3. pp. 546-551.
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RIS
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TY - JOUR
DO - 10.1021/ic048479+
UR - https://doi.org/10.1021/ic048479
TI - [BDTA]2[Cu(mnt)2]: An Almost Perfect One-Dimensional Magnetic Material
T2 - Inorganic Chemistry
AU - Staniland, Sarah S
AU - FUJITA, Wataru
AU - Umezono, Yoshikatsu
AU - Awaga, Kunio
AU - Camp, Philip E.
AU - Clark, Stewart J.
AU - Robertson, Neil J.
PY - 2005
DA - 2005/01/13
PB - American Chemical Society (ACS)
SP - 546-551
IS - 3
VL - 44
PMID - 15679383
SN - 0020-1669
SN - 1520-510X
ER -
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BibTex (up to 50 authors)
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@article{2005_Staniland,
author = {Sarah S Staniland and Wataru FUJITA and Yoshikatsu Umezono and Kunio Awaga and Philip E. Camp and Stewart J. Clark and Neil J. Robertson},
title = {[BDTA]2[Cu(mnt)2]: An Almost Perfect One-Dimensional Magnetic Material},
journal = {Inorganic Chemistry},
year = {2005},
volume = {44},
publisher = {American Chemical Society (ACS)},
month = {jan},
url = {https://doi.org/10.1021/ic048479 },
number = {3},
pages = {546--551},
doi = {10.1021/ic048479+}
}
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MLA
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Staniland, Sarah S., et al. “[BDTA]2[Cu(mnt)2]: An Almost Perfect One-Dimensional Magnetic Material.” Inorganic Chemistry, vol. 44, no. 3, Jan. 2005, pp. 546-551. https://doi.org/10.1021/ic048479 .