Infrared Spectra and Electronic Structure Calculations for the NUN(NN)1–5 and NU(NN)1–6 Complexes in Solid Argon
Publication type: Journal Article
Publication date: 2013-08-15
scimago Q1
wos Q1
SJR: 0.958
CiteScore: 7.4
Impact factor: 4.7
ISSN: 00201669, 1520510X
PubMed ID:
23944737
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Reactions of laser-ablated U atoms with N2 molecules in excess argon during co-deposition at 4 K gave intense NUN and weaker UN absorptions. Annealing increased progressions of new absorptions for the NUN(NN)1,2,3,4,5 and NU(NN)1,2,3,4,5,6 uranium nitride complexes. Small matrix shifts are observed when the secondary coordination layers around the primary NUN(NN)1,2,3,4,5 and NU(NN)1,2,3,4,5,6 complexes are changed from argon to nitrogen. Electronic structure and energy and frequency calculations provide support for the identification of these complexes and further characterization of the N≡U≡N and U≡N core molecules as terminal uranium nitrides with full triple bonds.
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Total citations:
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Citations from 2024:
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GOST
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Andrews L. et al. Infrared Spectra and Electronic Structure Calculations for the NUN(NN)1–5 and NU(NN)1–6 Complexes in Solid Argon // Inorganic Chemistry. 2013. Vol. 52. No. 17. pp. 9989-9993.
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Andrews L., Wang X., Gong Yu., Vlaisavljevich B., Gagliardi L. Infrared Spectra and Electronic Structure Calculations for the NUN(NN)1–5 and NU(NN)1–6 Complexes in Solid Argon // Inorganic Chemistry. 2013. Vol. 52. No. 17. pp. 9989-9993.
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TY - JOUR
DO - 10.1021/ic401857u
UR - https://doi.org/10.1021/ic401857u
TI - Infrared Spectra and Electronic Structure Calculations for the NUN(NN)1–5 and NU(NN)1–6 Complexes in Solid Argon
T2 - Inorganic Chemistry
AU - Andrews, Lester
AU - Wang, Xue-feng
AU - Gong, Yu
AU - Vlaisavljevich, Bess
AU - Gagliardi, Laura
PY - 2013
DA - 2013/08/15
PB - American Chemical Society (ACS)
SP - 9989-9993
IS - 17
VL - 52
PMID - 23944737
SN - 0020-1669
SN - 1520-510X
ER -
Cite this
BibTex (up to 50 authors)
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@article{2013_Andrews,
author = {Lester Andrews and Xue-feng Wang and Yu Gong and Bess Vlaisavljevich and Laura Gagliardi},
title = {Infrared Spectra and Electronic Structure Calculations for the NUN(NN)1–5 and NU(NN)1–6 Complexes in Solid Argon},
journal = {Inorganic Chemistry},
year = {2013},
volume = {52},
publisher = {American Chemical Society (ACS)},
month = {aug},
url = {https://doi.org/10.1021/ic401857u},
number = {17},
pages = {9989--9993},
doi = {10.1021/ic401857u}
}
Cite this
MLA
Copy
Andrews, Lester, et al. “Infrared Spectra and Electronic Structure Calculations for the NUN(NN)1–5 and NU(NN)1–6 Complexes in Solid Argon.” Inorganic Chemistry, vol. 52, no. 17, Aug. 2013, pp. 9989-9993. https://doi.org/10.1021/ic401857u.