Inorganic Chemistry, volume 52, issue 17, pages 9989-9993
Infrared Spectra and Electronic Structure Calculations for the NUN(NN)1–5 and NU(NN)1–6 Complexes in Solid Argon
Publication type: Journal Article
Publication date: 2013-08-15
Journal:
Inorganic Chemistry
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 4.6
ISSN: 00201669, 1520510X
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Reactions of laser-ablated U atoms with N2 molecules in excess argon during co-deposition at 4 K gave intense NUN and weaker UN absorptions. Annealing increased progressions of new absorptions for the NUN(NN)1,2,3,4,5 and NU(NN)1,2,3,4,5,6 uranium nitride complexes. Small matrix shifts are observed when the secondary coordination layers around the primary NUN(NN)1,2,3,4,5 and NU(NN)1,2,3,4,5,6 complexes are changed from argon to nitrogen. Electronic structure and energy and frequency calculations provide support for the identification of these complexes and further characterization of the N≡U≡N and U≡N core molecules as terminal uranium nitrides with full triple bonds.
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Citations by publishers
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9 publications, 42.86%
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- We do not take into account publications without a DOI.
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Andrews L. et al. Infrared Spectra and Electronic Structure Calculations for the NUN(NN)1–5 and NU(NN)1–6 Complexes in Solid Argon // Inorganic Chemistry. 2013. Vol. 52. No. 17. pp. 9989-9993.
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Andrews L., Wang X., Gong Yu., Vlaisavljevich B., Gagliardi L. Infrared Spectra and Electronic Structure Calculations for the NUN(NN)1–5 and NU(NN)1–6 Complexes in Solid Argon // Inorganic Chemistry. 2013. Vol. 52. No. 17. pp. 9989-9993.
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TY - JOUR
DO - 10.1021/ic401857u
UR - https://doi.org/10.1021/ic401857u
TI - Infrared Spectra and Electronic Structure Calculations for the NUN(NN)1–5 and NU(NN)1–6 Complexes in Solid Argon
T2 - Inorganic Chemistry
AU - Andrews, Lester
AU - Wang, Xue-feng
AU - Gong, Yu
AU - Vlaisavljevich, Bess
AU - Gagliardi, Laura
PY - 2013
DA - 2013/08/15 00:00:00
PB - American Chemical Society (ACS)
SP - 9989-9993
IS - 17
VL - 52
SN - 0020-1669
SN - 1520-510X
ER -
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@article{2013_Andrews,
author = {Lester Andrews and Xue-feng Wang and Yu Gong and Bess Vlaisavljevich and Laura Gagliardi},
title = {Infrared Spectra and Electronic Structure Calculations for the NUN(NN)1–5 and NU(NN)1–6 Complexes in Solid Argon},
journal = {Inorganic Chemistry},
year = {2013},
volume = {52},
publisher = {American Chemical Society (ACS)},
month = {aug},
url = {https://doi.org/10.1021/ic401857u},
number = {17},
pages = {9989--9993},
doi = {10.1021/ic401857u}
}
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Andrews, Lester, et al. “Infrared Spectra and Electronic Structure Calculations for the NUN(NN)1–5 and NU(NN)1–6 Complexes in Solid Argon.” Inorganic Chemistry, vol. 52, no. 17, Aug. 2013, pp. 9989-9993. https://doi.org/10.1021/ic401857u.