Inorganic Chemistry, volume 53, issue 18, pages 9463-9465
Carbon Dioxide Hydrosilylation Promoted by Cobalt Pincer Complexes
Publication type: Journal Article
Publication date: 2014-08-29
Journal:
Inorganic Chemistry
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 4.6
ISSN: 00201669, 1520510X
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
The addition of carbon dioxide to ((tBu)PNP)CoH [(tBu)PNP = 2,6-bis(di-tert-butylphosphinomethyl)pyridine] resulted in rapid insertion into the Co-H bond to form the corresponding κ(1)-formate complex, which has been structurally characterized. Treatment of ((tBu)PNP)CoH with PhSiH3 resulted in oxidative addition to form trans-((tBu)PNP)CoH2(SiH2Ph), which undergoes rapid exchange with excess free silane. With 0.5 mol % ((tBu)PNP)CoH, the catalytic hydrosilylation of CO2 with PhSiH3 to a mixture of oligomers containing silyl formate, bis(silyl)acetyl, and silyl ether subunits has been observed.
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1 publication, 0.85%
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- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Scheuermann M. L. et al. Carbon Dioxide Hydrosilylation Promoted by Cobalt Pincer Complexes // Inorganic Chemistry. 2014. Vol. 53. No. 18. pp. 9463-9465.
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Scheuermann M. L., Semproni S. P., Pappas I., Chirik P. J. Carbon Dioxide Hydrosilylation Promoted by Cobalt Pincer Complexes // Inorganic Chemistry. 2014. Vol. 53. No. 18. pp. 9463-9465.
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TY - JOUR
DO - 10.1021/ic501901n
UR - https://doi.org/10.1021/ic501901n
TI - Carbon Dioxide Hydrosilylation Promoted by Cobalt Pincer Complexes
T2 - Inorganic Chemistry
AU - Semproni, Scott P
AU - Scheuermann, Margaret L
AU - Pappas, Iraklis
AU - Chirik, Paul J.
PY - 2014
DA - 2014/08/29 00:00:00
PB - American Chemical Society (ACS)
SP - 9463-9465
IS - 18
VL - 53
SN - 0020-1669
SN - 1520-510X
ER -
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@article{2014_Scheuermann,
author = {Scott P Semproni and Margaret L Scheuermann and Iraklis Pappas and Paul J. Chirik},
title = {Carbon Dioxide Hydrosilylation Promoted by Cobalt Pincer Complexes},
journal = {Inorganic Chemistry},
year = {2014},
volume = {53},
publisher = {American Chemical Society (ACS)},
month = {aug},
url = {https://doi.org/10.1021/ic501901n},
number = {18},
pages = {9463--9465},
doi = {10.1021/ic501901n}
}
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Scheuermann, Margaret L., et al. “Carbon Dioxide Hydrosilylation Promoted by Cobalt Pincer Complexes.” Inorganic Chemistry, vol. 53, no. 18, Aug. 2014, pp. 9463-9465. https://doi.org/10.1021/ic501901n.