Carbon Dioxide Hydrosilylation Promoted by Cobalt Pincer Complexes
Publication type: Journal Article
Publication date: 2014-08-29
scimago Q1
wos Q1
SJR: 0.958
CiteScore: 7.4
Impact factor: 4.7
ISSN: 00201669, 1520510X
PubMed ID:
25171221
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
The addition of carbon dioxide to ((tBu)PNP)CoH [(tBu)PNP = 2,6-bis(di-tert-butylphosphinomethyl)pyridine] resulted in rapid insertion into the Co-H bond to form the corresponding κ(1)-formate complex, which has been structurally characterized. Treatment of ((tBu)PNP)CoH with PhSiH3 resulted in oxidative addition to form trans-((tBu)PNP)CoH2(SiH2Ph), which undergoes rapid exchange with excess free silane. With 0.5 mol % ((tBu)PNP)CoH, the catalytic hydrosilylation of CO2 with PhSiH3 to a mixture of oligomers containing silyl formate, bis(silyl)acetyl, and silyl ether subunits has been observed.
Found
Nothing found, try to update filter.
Found
Nothing found, try to update filter.
Top-30
Journals
|
2
4
6
8
10
12
14
|
|
|
Organometallics
13 publications, 10.08%
|
|
|
Chemistry - A European Journal
11 publications, 8.53%
|
|
|
ACS Catalysis
11 publications, 8.53%
|
|
|
Journal of the American Chemical Society
10 publications, 7.75%
|
|
|
Dalton Transactions
8 publications, 6.2%
|
|
|
ChemCatChem
6 publications, 4.65%
|
|
|
Inorganic Chemistry
6 publications, 4.65%
|
|
|
Catalysis Science and Technology
5 publications, 3.88%
|
|
|
Polyhedron
4 publications, 3.1%
|
|
|
Chemical Communications
4 publications, 3.1%
|
|
|
Chemistry Letters
3 publications, 2.33%
|
|
|
European Journal of Inorganic Chemistry
3 publications, 2.33%
|
|
|
Angewandte Chemie - International Edition
3 publications, 2.33%
|
|
|
Angewandte Chemie
3 publications, 2.33%
|
|
|
Inorganic Chemistry Frontiers
3 publications, 2.33%
|
|
|
Bulletin of the Chemical Society of Japan
2 publications, 1.55%
|
|
|
Organic Letters
2 publications, 1.55%
|
|
|
Journal of CO2 Utilization
2 publications, 1.55%
|
|
|
Chemical Reviews
2 publications, 1.55%
|
|
|
Green Chemistry
2 publications, 1.55%
|
|
|
SpringerBriefs in Molecular Science
2 publications, 1.55%
|
|
|
Catalysts
1 publication, 0.78%
|
|
|
Science China Chemistry
1 publication, 0.78%
|
|
|
Materials Research Express
1 publication, 0.78%
|
|
|
Israel Journal of Chemistry
1 publication, 0.78%
|
|
|
Chemical Record
1 publication, 0.78%
|
|
|
ChemSusChem
1 publication, 0.78%
|
|
|
Journal of Physical Chemistry A
1 publication, 0.78%
|
|
|
ACS Central Science
1 publication, 0.78%
|
|
|
2
4
6
8
10
12
14
|
Publishers
|
5
10
15
20
25
30
35
40
45
50
|
|
|
American Chemical Society (ACS)
47 publications, 36.43%
|
|
|
Wiley
32 publications, 24.81%
|
|
|
Royal Society of Chemistry (RSC)
25 publications, 19.38%
|
|
|
Elsevier
10 publications, 7.75%
|
|
|
Oxford University Press
5 publications, 3.88%
|
|
|
Springer Nature
4 publications, 3.1%
|
|
|
MDPI
1 publication, 0.78%
|
|
|
IOP Publishing
1 publication, 0.78%
|
|
|
Pleiades Publishing
1 publication, 0.78%
|
|
|
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 0.78%
|
|
|
OOO Zhurnal "Mendeleevskie Soobshcheniya"
1 publication, 0.78%
|
|
|
5
10
15
20
25
30
35
40
45
50
|
- We do not take into account publications without a DOI.
- Statistics recalculated weekly.
Are you a researcher?
Create a profile to get free access to personal recommendations for colleagues and new articles.
Metrics
129
Total citations:
129
Citations from 2024:
17
(13.18%)
Cite this
GOST |
RIS |
BibTex |
MLA
Cite this
GOST
Copy
Scheuermann M. L. et al. Carbon Dioxide Hydrosilylation Promoted by Cobalt Pincer Complexes // Inorganic Chemistry. 2014. Vol. 53. No. 18. pp. 9463-9465.
GOST all authors (up to 50)
Copy
Scheuermann M. L., Semproni S. P., Pappas I., Chirik P. J. Carbon Dioxide Hydrosilylation Promoted by Cobalt Pincer Complexes // Inorganic Chemistry. 2014. Vol. 53. No. 18. pp. 9463-9465.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/ic501901n
UR - https://doi.org/10.1021/ic501901n
TI - Carbon Dioxide Hydrosilylation Promoted by Cobalt Pincer Complexes
T2 - Inorganic Chemistry
AU - Scheuermann, Margaret L
AU - Semproni, Scott P
AU - Pappas, Iraklis
AU - Chirik, Paul J.
PY - 2014
DA - 2014/08/29
PB - American Chemical Society (ACS)
SP - 9463-9465
IS - 18
VL - 53
PMID - 25171221
SN - 0020-1669
SN - 1520-510X
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2014_Scheuermann,
author = {Margaret L Scheuermann and Scott P Semproni and Iraklis Pappas and Paul J. Chirik},
title = {Carbon Dioxide Hydrosilylation Promoted by Cobalt Pincer Complexes},
journal = {Inorganic Chemistry},
year = {2014},
volume = {53},
publisher = {American Chemical Society (ACS)},
month = {aug},
url = {https://doi.org/10.1021/ic501901n},
number = {18},
pages = {9463--9465},
doi = {10.1021/ic501901n}
}
Cite this
MLA
Copy
Scheuermann, Margaret L., et al. “Carbon Dioxide Hydrosilylation Promoted by Cobalt Pincer Complexes.” Inorganic Chemistry, vol. 53, no. 18, Aug. 2014, pp. 9463-9465. https://doi.org/10.1021/ic501901n.