Inorganic Chemistry

, том 37 , издание 9 , страницы 2317-2319

Structural Characterization of [(2,6-Prⁱ₂C₆H₃)NC(Me)C(H)C(Me)N(2,6-Prⁱ₂C₆H₃)K·PhCH₃]_∞: A Heavy Alkali Metal Diazapentadienyl Complex

Тип публикации: Journal Article

Дата публикации: 1998-04-17

American Chemical Society (ACS)

Inorganic Chemistry

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SJR: 0.879

CiteScore: 7.5

Impact factor: 4.6

ISSN: 00201669, 1520510X

DOI: 10.1021/ic970956j

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PubMed ID: 11670390

Inorganic Chemistry

Physical and Theoretical Chemistry

Краткое описание

The compound pictured, an arene-soluble potassium salt of a sterically demanding diazapentadienyl ligand, is accessible in two short steps from commercially available, inexpensive regents. The anion may compete with amidinate or Cp* ligands in solubilizing and controlling the environment of metal ions; it effectively engulfs the potassium ion while appearing to be merely bidentate. Only weak single η5 contacts to substituted phenyl groups link the monomers.

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Clegg W. et al. Structural Characterization of [(2,6-Pri2C6H3)NC(Me)C(H)C(Me)N(2,6-Pri2C6H3)K·PhCH3]∞: A Heavy Alkali Metal Diazapentadienyl Complex // Inorganic Chemistry. 1998. Vol. 37. No. 9. pp. 2317-2319.

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Clegg W., Cope E. K., EDWARDS A. J., Mair F. S. Structural Characterization of [(2,6-Pri2C6H3)NC(Me)C(H)C(Me)N(2,6-Pri2C6H3)K·PhCH3]∞: A Heavy Alkali Metal Diazapentadienyl Complex // Inorganic Chemistry. 1998. Vol. 37. No. 9. pp. 2317-2319.

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TY - JOUR

DO - 10.1021/ic970956j

UR - https://doi.org/10.1021/ic970956j

TI - Structural Characterization of [(2,6-Pri2C6H3)NC(Me)C(H)C(Me)N(2,6-Pri2C6H3)K·PhCH3]∞: A Heavy Alkali Metal Diazapentadienyl Complex

T2 - Inorganic Chemistry

AU - Clegg, William

AU - Cope, Elaine K

AU - EDWARDS, ANDREW J.

AU - Mair, Francis S.

PY - 1998

DA - 1998/04/17

PB - American Chemical Society (ACS)

SP - 2317-2319

IS - 9

VL - 37

PMID - 11670390

SN - 0020-1669

SN - 1520-510X

ER -

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@article{1998_Clegg,

author = {William Clegg and Elaine K Cope and ANDREW J. EDWARDS and Francis S. Mair},

title = {Structural Characterization of [(2,6-Pri2C6H3)NC(Me)C(H)C(Me)N(2,6-Pri2C6H3)K·PhCH3]∞: A Heavy Alkali Metal Diazapentadienyl Complex},

journal = {Inorganic Chemistry},

year = {1998},

volume = {37},

publisher = {American Chemical Society (ACS)},

month = {apr},

url = {https://doi.org/10.1021/ic970956j},

number = {9},

pages = {2317--2319},

doi = {10.1021/ic970956j}

}

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Clegg, William, et al. “Structural Characterization of [(2,6-Pri2C6H3)NC(Me)C(H)C(Me)N(2,6-Pri2C6H3)K·PhCH3]∞: A Heavy Alkali Metal Diazapentadienyl Complex.” Inorganic Chemistry, vol. 37, no. 9, Apr. 1998, pp. 2317-2319. https://doi.org/10.1021/ic970956j.

Издатель

American Chemical Society (ACS)

Журнал

Inorganic Chemistry

SCImago Q1

WOS Q1

БС1