Reduced Anionic Mn12 Molecules with Half-Integer Ground States as Single-Molecule Magnets
Sheila M.J. Aubin
1
,
Ziming Sun
1
,
Luca Pardi
1
,
J. Krzystek
1
,
KIRSTEN FOLTING
1
,
LOUIS CLAUDE BRUNEL
1
,
Arnold L. Rheingold
1
,
George Christou
1
,
David N. Hendrickson
1
Publication type: Journal Article
Publication date: 1999-10-26
scimago Q1
wos Q1
SJR: 0.958
CiteScore: 7.4
Impact factor: 4.7
ISSN: 00201669, 1520510X
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
The preparation, characterization, and X-ray structure are reported for the single-molecule magnet (PPh4)[Mn12O12(O2CPh)16(H2O)4]·8(CH2Cl2) (2). Complex 2 crystallizes in the triclinic space group P1, which at 213 K has a = 17.2329(2), b = 17.8347(2), c = 26.8052(2) A, α = 90.515(2), β = 94.242(2), γ = 101.437(2)°, and Z = 2. The salt consists of PPh4+ cations and [Mn12O12(O2CPh)16(H2O)4]- anions. The (Mn12O12)15+ core of the anion is formed by an external ring of eight Mn atoms bridged by μ3−O2- ions to an internal tetrahedron of four Mn atoms. Because of disorder in both phenyl rings and solvate molecules, it was difficult to use bond valence sum values to determine definitively the oxidation state of each Mn atom. There is a Mn4O4 cubane unit in the internal part of the molecule and these Mn atoms are all MnIV ions. For the eight “external” Mn atoms the bond valence sum values did not define well their oxidation states. For these eight Mn atoms, it was not possible to determine whether a trapped-valen...
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Total citations:
598
Citations from 2025:
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Aubin S. M. et al. Reduced Anionic Mn12 Molecules with Half-Integer Ground States as Single-Molecule Magnets // Inorganic Chemistry. 1999. Vol. 38. No. 23. pp. 5329-5340.
GOST all authors (up to 50)
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Aubin S. M., Sun Z., Pardi L., Krzystek J., FOLTING K., BRUNEL L. C., Rheingold A. L., Christou G., Hendrickson D. N. Reduced Anionic Mn12 Molecules with Half-Integer Ground States as Single-Molecule Magnets // Inorganic Chemistry. 1999. Vol. 38. No. 23. pp. 5329-5340.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/ic990613g
UR - https://doi.org/10.1021/ic990613g
TI - Reduced Anionic Mn12 Molecules with Half-Integer Ground States as Single-Molecule Magnets
T2 - Inorganic Chemistry
AU - Aubin, Sheila M.J.
AU - Sun, Ziming
AU - Pardi, Luca
AU - Krzystek, J.
AU - FOLTING, KIRSTEN
AU - BRUNEL, LOUIS CLAUDE
AU - Rheingold, Arnold L.
AU - Christou, George
AU - Hendrickson, David N.
PY - 1999
DA - 1999/10/26
PB - American Chemical Society (ACS)
SP - 5329-5340
IS - 23
VL - 38
SN - 0020-1669
SN - 1520-510X
ER -
Cite this
BibTex (up to 50 authors)
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@article{1999_Aubin,
author = {Sheila M.J. Aubin and Ziming Sun and Luca Pardi and J. Krzystek and KIRSTEN FOLTING and LOUIS CLAUDE BRUNEL and Arnold L. Rheingold and George Christou and David N. Hendrickson},
title = {Reduced Anionic Mn12 Molecules with Half-Integer Ground States as Single-Molecule Magnets},
journal = {Inorganic Chemistry},
year = {1999},
volume = {38},
publisher = {American Chemical Society (ACS)},
month = {oct},
url = {https://doi.org/10.1021/ic990613g},
number = {23},
pages = {5329--5340},
doi = {10.1021/ic990613g}
}
Cite this
MLA
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Aubin, Sheila M.J., et al. “Reduced Anionic Mn12 Molecules with Half-Integer Ground States as Single-Molecule Magnets.” Inorganic Chemistry, vol. 38, no. 23, Oct. 1999, pp. 5329-5340. https://doi.org/10.1021/ic990613g.