том 40 издание 3 страницы 533-539

In situ NMR observation of mono- and binuclear rhodium dihydride complexes using parahydrogen-induced polarization.

Тип публикацииJournal Article
Дата публикации2001-01-01
scimago Q1
wos Q1
БС1
SJR0.958
CiteScore7.4
Impact factor4.7
ISSN00201669, 1520510X
Inorganic Chemistry
Physical and Theoretical Chemistry
Краткое описание
Starting from the binuclear complex [RhCl(NBD)]2 (NBD = 2,5-norbornadiene) in the presence of the phosphines L = PMe3, PMe2Ph, PMePh2, PEt3, PEt2Ph, PEtPh2, or P(n-butyl)3, various mononuclear dihydrides of the type Rh(H)2CIL3, i.e., those of the homogeneous hydrogenation catalysts RhCIL3, have been obtained upon addition of parahydrogen, and their 1H NMR spectra have been investigated using parahydrogen-induced polarization (PHIP). Furthermore, the two binuclear complexes (H)(Cl)Rh(PMe3)2(mu-Cl)(mu-H)Rh(PMe3) and (H)(Cl)Rh(PMe2Ph)2(mu-Cl)(mu-H)Rh(PMe2Ph) have been detected and characterized by means of this in situ NMR method. Analogous complexes with trifluoroacetate instead of chloride, i.e., Rh(H)2(CF3COO)L3, have been generated in situ starting from Rh(NBD)(acac) in the presence of trifluoroacetic acid in combination with the phosphines L = PPh3, PEt2Ph, PEt3, and P(n-butyl)3, and their 1H NMR parameters have been determined.
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ГОСТ |
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Koch A., Bargon J. In situ NMR observation of mono- and binuclear rhodium dihydride complexes using parahydrogen-induced polarization. // Inorganic Chemistry. 2001. Vol. 40. No. 3. pp. 533-539.
ГОСТ со всеми авторами (до 50) Скопировать
Koch A., Bargon J. In situ NMR observation of mono- and binuclear rhodium dihydride complexes using parahydrogen-induced polarization. // Inorganic Chemistry. 2001. Vol. 40. No. 3. pp. 533-539.
RIS |
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TY - JOUR
DO - 10.1021/ic991319r
UR - https://doi.org/10.1021/ic991319r
TI - In situ NMR observation of mono- and binuclear rhodium dihydride complexes using parahydrogen-induced polarization.
T2 - Inorganic Chemistry
AU - Koch, Andreas
AU - Bargon, Joachim
PY - 2001
DA - 2001/01/01
PB - American Chemical Society (ACS)
SP - 533-539
IS - 3
VL - 40
PMID - 11209612
SN - 0020-1669
SN - 1520-510X
ER -
BibTex |
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BibTex (до 50 авторов) Скопировать
@article{2001_Koch,
author = {Andreas Koch and Joachim Bargon},
title = {In situ NMR observation of mono- and binuclear rhodium dihydride complexes using parahydrogen-induced polarization.},
journal = {Inorganic Chemistry},
year = {2001},
volume = {40},
publisher = {American Chemical Society (ACS)},
month = {jan},
url = {https://doi.org/10.1021/ic991319r},
number = {3},
pages = {533--539},
doi = {10.1021/ic991319r}
}
MLA
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Koch, Andreas, and Joachim Bargon. “In situ NMR observation of mono- and binuclear rhodium dihydride complexes using parahydrogen-induced polarization..” Inorganic Chemistry, vol. 40, no. 3, Jan. 2001, pp. 533-539. https://doi.org/10.1021/ic991319r.