The Influence of Phase Behavior on Reactions at Supercritical Conditions: The Hydrogenation of α-Pinene
Тип публикации: Journal Article
Дата публикации: 2001-05-17
scimago Q1
wos Q2
БС1
SJR: 0.828
CiteScore: 6.7
Impact factor: 3.9
ISSN: 08885885, 15205045
General Chemistry
General Chemical Engineering
Industrial and Manufacturing Engineering
Краткое описание
In this paper, results on the hydrogenation of α-pinene, a liquid reactant, in supercritical (SC) CO2 are presented. Visual observation of phase equilibria under the conditions of the reaction experiments was also performed. Much faster reaction rates were obtained when a two-phase system was present in the reactor than when a homogeneous, one-phase situation occurred. This phenomenon is attributed to the fact that SC CO2 can dissolve extensively in the liquid reactant, leading to the formation of an “expanded liquid”, which can dissolve large quantities of hydrogen. This seems to be the first time that this type of behavior is reported in the literature.
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ГОСТ
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Chouchi D. et al. The Influence of Phase Behavior on Reactions at Supercritical Conditions: The Hydrogenation of α-Pinene // Industrial & Engineering Chemistry Research. 2001. Vol. 40. No. 12. pp. 2551-2554.
ГОСТ со всеми авторами (до 50)
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Chouchi D., Gourgouillon D., Courel M., Vital J., Ponte M. N. D. The Influence of Phase Behavior on Reactions at Supercritical Conditions: The Hydrogenation of α-Pinene // Industrial & Engineering Chemistry Research. 2001. Vol. 40. No. 12. pp. 2551-2554.
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RIS
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TY - JOUR
DO - 10.1021/ie000859p
UR - https://doi.org/10.1021/ie000859p
TI - The Influence of Phase Behavior on Reactions at Supercritical Conditions: The Hydrogenation of α-Pinene
T2 - Industrial & Engineering Chemistry Research
AU - Chouchi, Dalida
AU - Gourgouillon, Didier
AU - Courel, Mathilde
AU - Vital, Joaquim
AU - Ponte, Manuel Nunes da
PY - 2001
DA - 2001/05/17
PB - American Chemical Society (ACS)
SP - 2551-2554
IS - 12
VL - 40
SN - 0888-5885
SN - 1520-5045
ER -
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BibTex (до 50 авторов)
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@article{2001_Chouchi,
author = {Dalida Chouchi and Didier Gourgouillon and Mathilde Courel and Joaquim Vital and Manuel Nunes da Ponte},
title = {The Influence of Phase Behavior on Reactions at Supercritical Conditions: The Hydrogenation of α-Pinene},
journal = {Industrial & Engineering Chemistry Research},
year = {2001},
volume = {40},
publisher = {American Chemical Society (ACS)},
month = {may},
url = {https://doi.org/10.1021/ie000859p},
number = {12},
pages = {2551--2554},
doi = {10.1021/ie000859p}
}
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MLA
Скопировать
Chouchi, Dalida, et al. “The Influence of Phase Behavior on Reactions at Supercritical Conditions: The Hydrogenation of α-Pinene.” Industrial & Engineering Chemistry Research, vol. 40, no. 12, May. 2001, pp. 2551-2554. https://doi.org/10.1021/ie000859p.