Phenol Alkylation with 1-Octene on Solid Acid Catalysts
1
Fischer-Tropsch Refinery Catalysis, Sasol Technology Research and Development, P.O. Box 1, Sasolburg 1947, South Africa
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Publication type: Journal Article
Publication date: 2007-09-18
scimago Q1
wos Q2
SJR: 0.828
CiteScore: 6.7
Impact factor: 3.9
ISSN: 08885885, 15205045
General Chemistry
General Chemical Engineering
Industrial and Manufacturing Engineering
Abstract
Solid phosphoric acid (SPA), silicated amorphous silica−alumina (ASA) catalysts (1.5−70% SiO2), and zeolites beta (BEA), mordenite (MOR), and ZSM-5 (MFI) were investigated for the alkylation of phenol with 1-octene. All catalysts were active for phenol alkylation at 200 °C in batch reactors, with olefin oligomerization being the main side reaction. All catalysts produced alkylphenols and phenyl ethers and had a low initial selectivity to o-octylphenol. Monoalkylated product selectivity on silicated ASA may be related to the orientating effect of the silicated catalyst surface but could not be related to the acid strength or alumina content of the catalysts. Evidence is also presented that indicates that an ester-based mechanism is active over silicated ASA. Monoalkylated product selectivity on zeolites could be correlated to the average pore size of the catalysts (shape selectivity). Multiple alkylation was found on SPA, Siral-28M, and the zeolite catalysts, with both acid strength and pore size determini...
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Total citations:
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Citations from 2024:
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(11.11%)
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GOST
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De Klerk A., Nel R. J. J. Phenol Alkylation with 1-Octene on Solid Acid Catalysts // Industrial & Engineering Chemistry Research. 2007. Vol. 46. No. 22. pp. 7066-7072.
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De Klerk A., Nel R. J. J. Phenol Alkylation with 1-Octene on Solid Acid Catalysts // Industrial & Engineering Chemistry Research. 2007. Vol. 46. No. 22. pp. 7066-7072.
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RIS
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TY - JOUR
DO - 10.1021/ie0706459
UR - https://doi.org/10.1021/ie0706459
TI - Phenol Alkylation with 1-Octene on Solid Acid Catalysts
T2 - Industrial & Engineering Chemistry Research
AU - De Klerk, Arno
AU - Nel, Reinier J J
PY - 2007
DA - 2007/09/18
PB - American Chemical Society (ACS)
SP - 7066-7072
IS - 22
VL - 46
SN - 0888-5885
SN - 1520-5045
ER -
Cite this
BibTex (up to 50 authors)
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@article{2007_De Klerk,
author = {Arno De Klerk and Reinier J J Nel},
title = {Phenol Alkylation with 1-Octene on Solid Acid Catalysts},
journal = {Industrial & Engineering Chemistry Research},
year = {2007},
volume = {46},
publisher = {American Chemical Society (ACS)},
month = {sep},
url = {https://doi.org/10.1021/ie0706459},
number = {22},
pages = {7066--7072},
doi = {10.1021/ie0706459}
}
Cite this
MLA
Copy
De Klerk, Arno, and Reinier J J Nel. “Phenol Alkylation with 1-Octene on Solid Acid Catalysts.” Industrial & Engineering Chemistry Research, vol. 46, no. 22, Sep. 2007, pp. 7066-7072. https://doi.org/10.1021/ie0706459.