Homogeneous Hydroformylation of 1-Octene in Supercritical Carbon Dioxide with [RhH(CO)(P(p-CF3C6H4)3)3]
Тип публикации: Journal Article
Дата публикации: 1999-04-16
SCImago Q1
WOS Q2
БС1
SJR: 0.756
CiteScore: 6.6
Impact factor: 3.9
ISSN: 08885885, 15205045
General Chemistry
General Chemical Engineering
Industrial and Manufacturing Engineering
Краткое описание
A novel catalyst, RhH(CO)(P(p-CF3Ph)3)3, was synthesized for homogeneous catalytic hydroformylation of olefins in supercritical carbon dioxide. The incorporation of p-(trifluoromethyl) groups to the conventional hydroformylation catalyst, HRhCO(PPh3)3, provided enhanced solubility in supercritical carbon dioxide while maintaining catalyst activity and selectivity in the hydroformylation of 1-octene. The reaction rate showed a first-order dependency on the catalyst concentration. The total system pressure had no effect on either the reaction rate or selectivity. However, selectivity was found to depend on the catalyst concentration.
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ГОСТ
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Palo D. R., Erkey C. Homogeneous Hydroformylation of 1-Octene in Supercritical Carbon Dioxide with [RhH(CO)(P(p-CF3C6H4)3)3] // Industrial & Engineering Chemistry Research. 1999. Vol. 38. No. 5. pp. 2163-2165.
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Palo D. R., Erkey C. Homogeneous Hydroformylation of 1-Octene in Supercritical Carbon Dioxide with [RhH(CO)(P(p-CF3C6H4)3)3] // Industrial & Engineering Chemistry Research. 1999. Vol. 38. No. 5. pp. 2163-2165.
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TY - JOUR
DO - 10.1021/ie980757n
UR - https://pubs.acs.org/doi/10.1021/ie980757n
TI - Homogeneous Hydroformylation of 1-Octene in Supercritical Carbon Dioxide with [RhH(CO)(P(p-CF3C6H4)3)3]
T2 - Industrial & Engineering Chemistry Research
AU - Palo, Daniel R.
AU - Erkey, Can
PY - 1999
DA - 1999/04/16
PB - American Chemical Society (ACS)
SP - 2163-2165
IS - 5
VL - 38
SN - 0888-5885
SN - 1520-5045
ER -
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BibTex (до 50 авторов)
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@article{1999_Palo,
author = {Daniel R. Palo and Can Erkey},
title = {Homogeneous Hydroformylation of 1-Octene in Supercritical Carbon Dioxide with [RhH(CO)(P(p-CF3C6H4)3)3]},
journal = {Industrial & Engineering Chemistry Research},
year = {1999},
volume = {38},
publisher = {American Chemical Society (ACS)},
month = {apr},
url = {https://pubs.acs.org/doi/10.1021/ie980757n},
number = {5},
pages = {2163--2165},
doi = {10.1021/ie980757n}
}
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MLA
Скопировать
Palo, Daniel R., and Can Erkey. “Homogeneous Hydroformylation of 1-Octene in Supercritical Carbon Dioxide with [RhH(CO)(P(p-CF3C6H4)3)3].” Industrial & Engineering Chemistry Research, vol. 38, no. 5, Apr. 1999, pp. 2163-2165. https://pubs.acs.org/doi/10.1021/ie980757n.
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