Steady-state and time-resolved direct detection EPR spectra of fullerene triplets in liquid solution and glassy matrixes: evidence for a dynamic Jahn-Teller effect in triplet C60
Тип публикации: Journal Article
Дата публикации: 1992-06-01
SJR: —
CiteScore: —
Impact factor: —
ISSN: 00223654, 15415740
Physical and Theoretical Chemistry
General Engineering
Краткое описание
UV irradiation of methylcyclohexane solutions of C 60 produces a very narrow, transient EPR absorption which is assigned to the first excited triplet state of C 60 . The line widthof only 0.14 G, uncommon for motionally narrowed triplet EPR spectra, is attributed to a very rapid interchange of the magnetic axes by pseudorotation converting the degenerate Jahn-Teller states into each other. Time-resolved, direct-absorption EPR measurements with a time resolution of 0.5 μs support this conclusion
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ГОСТ
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Closs G. L. et al. Steady-state and time-resolved direct detection EPR spectra of fullerene triplets in liquid solution and glassy matrixes: evidence for a dynamic Jahn-Teller effect in triplet C60 // The Journal of Physical Chemistry. 1992. Vol. 96. No. 13. pp. 5228-5231.
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Closs G. L., Chakravarthy M., Zhang D., Krusic P. J., Hill S. A., Wasserman E. Steady-state and time-resolved direct detection EPR spectra of fullerene triplets in liquid solution and glassy matrixes: evidence for a dynamic Jahn-Teller effect in triplet C60 // The Journal of Physical Chemistry. 1992. Vol. 96. No. 13. pp. 5228-5231.
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TY - JOUR
DO - 10.1021/j100192a011
UR - https://doi.org/10.1021/j100192a011
TI - Steady-state and time-resolved direct detection EPR spectra of fullerene triplets in liquid solution and glassy matrixes: evidence for a dynamic Jahn-Teller effect in triplet C60
T2 - The Journal of Physical Chemistry
AU - Closs, Gerhard L
AU - Chakravarthy, M.
AU - Zhang, Daisy
AU - Krusic, Paul J.
AU - Hill, Steven A.
AU - Wasserman, Edel
PY - 1992
DA - 1992/06/01
PB - American Chemical Society (ACS)
SP - 5228-5231
IS - 13
VL - 96
SN - 0022-3654
SN - 1541-5740
ER -
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@article{1992_Closs,
author = {Gerhard L Closs and M. Chakravarthy and Daisy Zhang and Paul J. Krusic and Steven A. Hill and Edel Wasserman},
title = {Steady-state and time-resolved direct detection EPR spectra of fullerene triplets in liquid solution and glassy matrixes: evidence for a dynamic Jahn-Teller effect in triplet C60},
journal = {The Journal of Physical Chemistry},
year = {1992},
volume = {96},
publisher = {American Chemical Society (ACS)},
month = {jun},
url = {https://doi.org/10.1021/j100192a011},
number = {13},
pages = {5228--5231},
doi = {10.1021/j100192a011}
}
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MLA
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Closs, Gerhard L., et al. “Steady-state and time-resolved direct detection EPR spectra of fullerene triplets in liquid solution and glassy matrixes: evidence for a dynamic Jahn-Teller effect in triplet C60.” The Journal of Physical Chemistry, vol. 96, no. 13, Jun. 1992, pp. 5228-5231. https://doi.org/10.1021/j100192a011.