Stable 2-vinylsiliranes
Тип публикации: Journal Article
Дата публикации: 1991-05-01
scimago Q1
wos Q1
БС1
SJR: 5.489
CiteScore: 24.4
Impact factor: 15.6
ISSN: 00027863, 15205126
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Краткое описание
Seven 2-vinyl-1,1-dimesitylsiliranes, stable at room temperature over months, have been synthesized from the addition of dimesitylsilylene to 2,3-dimethylbutadiene, 2-methylbutadiene, trans, trans-2,4-hexadiene, cis, cis-2,4-hexadiene, cis, cis-2,4-hexadiene, and cis,-trans-2,4-hexadiene. Addition of dimesitylsilylene to the π bond of the diene was stereospecific as indicated by 29 Si NMR. Secondary photodecomposition of 2-vinylsiliranes containing a vinylic hydrogen α to the silirane ring led to 2,3-dienylsilanes. Formation of cis-2,5-dimethyl-1,1-dimesitylsilacyclopent-3-ene from photolysis of solutions containing trans, trans-2,4-hexadiene, 2,2-dimesitylhexamethyltrisilane, and trans-2-methyl-3-(1-trans-propenyl)-1,1-dimesitylsilirane was stereospecific
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ГОСТ
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Zhang S. R., Conlin R. T. Stable 2-vinylsiliranes // Journal of the American Chemical Society. 1991. Vol. 113. No. 11. pp. 4272-4278.
ГОСТ со всеми авторами (до 50)
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Zhang S. R., Conlin R. T. Stable 2-vinylsiliranes // Journal of the American Chemical Society. 1991. Vol. 113. No. 11. pp. 4272-4278.
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RIS
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TY - JOUR
DO - 10.1021/ja00011a033
UR - https://doi.org/10.1021/ja00011a033
TI - Stable 2-vinylsiliranes
T2 - Journal of the American Chemical Society
AU - Zhang, Shun Rong
AU - Conlin, R T
PY - 1991
DA - 1991/05/01
PB - American Chemical Society (ACS)
SP - 4272-4278
IS - 11
VL - 113
SN - 0002-7863
SN - 1520-5126
ER -
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@article{1991_Zhang,
author = {Shun Rong Zhang and R T Conlin},
title = {Stable 2-vinylsiliranes},
journal = {Journal of the American Chemical Society},
year = {1991},
volume = {113},
publisher = {American Chemical Society (ACS)},
month = {may},
url = {https://doi.org/10.1021/ja00011a033},
number = {11},
pages = {4272--4278},
doi = {10.1021/ja00011a033}
}
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MLA
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Zhang, Shun Rong, and R T Conlin. “Stable 2-vinylsiliranes.” Journal of the American Chemical Society, vol. 113, no. 11, May. 1991, pp. 4272-4278. https://doi.org/10.1021/ja00011a033.