Chiral organolanthanide complexes for enantioselective olefin hydrogenation
Тип публикации: Journal Article
Дата публикации: 1992-03-01
SCImago Q1
Tоп 10% SCImago
WOS Q1
БС1
SJR: 5.491
CiteScore: 22
Impact factor: 16.6
ISSN: 00027863, 15205126
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Краткое описание
Organolanthanides with Cp{prime}{sub 2}Ln, R{sub 2}SiCp{double_prime} {sub 2}Ln, and R{sub 2}SiCpCp{double_prime}Ln supporting ligation (Cp{prime}={eta}{sup 5}-Me{sub 5}C{sub 5}; R = alkyl; Cp {double_prime} = {eta}{sup 5}-Me{sub 4}C{sub 5}){sup 1{minus}} catalyze olefin transformations. These characteristics caused the authors to investigate the question of whether f-element coordination geometries can elicit asymmetric transformations. A chelating ligand system designed to preserve Cp{prime}{sub 2}Ln stereoelectronic properties is presented by the authors. This system provides a rigid, chiral template for lateral/transverse substrate enantioface discrimination (A,B). Four related enantioselective organosamarium hydrogenation catalysts are considered. 25 refs., 1 fig.
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MLA
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ГОСТ
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Conticello V. P. et al. Chiral organolanthanide complexes for enantioselective olefin hydrogenation // Journal of the American Chemical Society. 1992. Vol. 114. No. 7. pp. 2761-2762.
ГОСТ со всеми авторами (до 50)
Скопировать
Conticello V. P., Brard L., Giardello M. A., Tsuji Y., Sabat M., Stern C., Marks T. Chiral organolanthanide complexes for enantioselective olefin hydrogenation // Journal of the American Chemical Society. 1992. Vol. 114. No. 7. pp. 2761-2762.
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RIS
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TY - JOUR
DO - 10.1021/ja00033a085
UR - https://doi.org/10.1021/ja00033a085
TI - Chiral organolanthanide complexes for enantioselective olefin hydrogenation
T2 - Journal of the American Chemical Society
AU - Conticello, Vincent P.
AU - Brard, Laurent
AU - Giardello, Michael A
AU - Tsuji, Yasushi
AU - Sabat, Michal
AU - Stern, Charlotte
AU - Marks, Tobin
PY - 1992
DA - 1992/03/01
PB - American Chemical Society (ACS)
SP - 2761-2762
IS - 7
VL - 114
SN - 0002-7863
SN - 1520-5126
ER -
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BibTex (до 50 авторов)
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@article{1992_Conticello,
author = {Vincent P. Conticello and Laurent Brard and Michael A Giardello and Yasushi Tsuji and Michal Sabat and Charlotte Stern and Tobin Marks},
title = {Chiral organolanthanide complexes for enantioselective olefin hydrogenation},
journal = {Journal of the American Chemical Society},
year = {1992},
volume = {114},
publisher = {American Chemical Society (ACS)},
month = {mar},
url = {https://doi.org/10.1021/ja00033a085},
number = {7},
pages = {2761--2762},
doi = {10.1021/ja00033a085}
}
Цитировать
MLA
Скопировать
Conticello, Vincent P., et al. “Chiral organolanthanide complexes for enantioselective olefin hydrogenation.” Journal of the American Chemical Society, vol. 114, no. 7, Mar. 1992, pp. 2761-2762. https://doi.org/10.1021/ja00033a085.
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