Photochemical ring-opening reactions are complete in picoseconds: a time-resolved UV resonance Raman study of 1,3-cyclohexadiene
Тип публикации: Journal Article
Дата публикации: 1993-06-01
SCImago Q1
Tоп 10% SCImago
WOS Q1
БС1
SJR: 5.491
CiteScore: 22
Impact factor: 16.6
ISSN: 00027863, 15205126
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Краткое описание
Photoproduct formation, vibrational, and conformational relaxation kinetics in the photochemical ring-openings of 1,3-cyclohexadiene (CHD) and α-phellandrene (α-PHE) are determined by picosecond, time-resolved UV Stokes and anti-Stokes resonance Raman spectroscopy. The frequency-doubled output from an amplified, synchronously pumped dye laser system was used to perform transient, two-color resonance Raman Stokes experiments on the photoconversion of CHD to cis-hexatriene (c-HT) and of α-PHE to 3,7-dimethyl-1,3,5-octatriene (OT). The appearance time of the Stokes scattering from ground-state c-HT is 6±1 ps, while that of OT is 11±2 ps. In both reactions, the photoproduct anti-Stokes ethylenic intensity appears with a time constant of 8±2 ps and decays in 9±2 ps
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Reid P. J. et al. Photochemical ring-opening reactions are complete in picoseconds: a time-resolved UV resonance Raman study of 1,3-cyclohexadiene // Journal of the American Chemical Society. 1993. Vol. 115. No. 11. pp. 4754-4763.
ГОСТ со всеми авторами (до 50)
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Reid P. J., Doig S. J., Wickham S. D., Mathies R. A. Photochemical ring-opening reactions are complete in picoseconds: a time-resolved UV resonance Raman study of 1,3-cyclohexadiene // Journal of the American Chemical Society. 1993. Vol. 115. No. 11. pp. 4754-4763.
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TY - JOUR
DO - 10.1021/ja00064a040
UR - https://doi.org/10.1021/ja00064a040
TI - Photochemical ring-opening reactions are complete in picoseconds: a time-resolved UV resonance Raman study of 1,3-cyclohexadiene
T2 - Journal of the American Chemical Society
AU - Reid, Philip J.
AU - Doig, Stephen J
AU - Wickham, Steven D
AU - Mathies, Richard A.
PY - 1993
DA - 1993/06/01
PB - American Chemical Society (ACS)
SP - 4754-4763
IS - 11
VL - 115
SN - 0002-7863
SN - 1520-5126
ER -
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BibTex (до 50 авторов)
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@article{1993_Reid,
author = {Philip J. Reid and Stephen J Doig and Steven D Wickham and Richard A. Mathies},
title = {Photochemical ring-opening reactions are complete in picoseconds: a time-resolved UV resonance Raman study of 1,3-cyclohexadiene},
journal = {Journal of the American Chemical Society},
year = {1993},
volume = {115},
publisher = {American Chemical Society (ACS)},
month = {jun},
url = {https://doi.org/10.1021/ja00064a040},
number = {11},
pages = {4754--4763},
doi = {10.1021/ja00064a040}
}
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MLA
Скопировать
Reid, Philip J., et al. “Photochemical ring-opening reactions are complete in picoseconds: a time-resolved UV resonance Raman study of 1,3-cyclohexadiene.” Journal of the American Chemical Society, vol. 115, no. 11, Jun. 1993, pp. 4754-4763. https://doi.org/10.1021/ja00064a040.
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