Double-decker actinide porphyrins and phthalocyanines. Synthesis and spectroscopic characterization of neutral, oxidized, and reduced homo- and heteroleptic complexes
Тип публикации: Journal Article
Дата публикации: 1993-09-01
scimago Q1
wos Q1
БС1
SJR: 5.489
CiteScore: 24.4
Impact factor: 15.6
ISSN: 00027863, 15205126
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Краткое описание
The synthesis, spectroscopic characterization, and electrochemistry of 26 different neutral and singly-oxidized homoleptic and heteroleptic actinide double-decker complexes are reported. The investigated compounds are represented as [M(P) 2 ] n , [M(P)(P')] n , [M(Pc) 2 ] n , and [M(P)(Pc)] n where n=0 or 1+, M=U or Th, Pc=the dianion of phthalocyanine, and P or P'=the dianions of octaethylporphyrin (OEP), tetraphenylporphyrin (TPP), or tetra-p-tolylporphyrin (TpTP). Each neutral compound was characterized by 1 H NMR, UV-visible, and IR spectroscopy and comparisons made to the cationic singly-oxidized double-decker derivatives which were chemically generated and isolated as a SbCl 6 - salt
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Kadish K. M. et al. Double-decker actinide porphyrins and phthalocyanines. Synthesis and spectroscopic characterization of neutral, oxidized, and reduced homo- and heteroleptic complexes // Journal of the American Chemical Society. 1993. Vol. 115. No. 18. pp. 8153-8166.
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Kadish K. M., Moninot G., Hu Y., Dubois D., Ibnlfassi A., Barbe J. M., Guilard R. Double-decker actinide porphyrins and phthalocyanines. Synthesis and spectroscopic characterization of neutral, oxidized, and reduced homo- and heteroleptic complexes // Journal of the American Chemical Society. 1993. Vol. 115. No. 18. pp. 8153-8166.
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TY - JOUR
DO - 10.1021/ja00071a028
UR - https://doi.org/10.1021/ja00071a028
TI - Double-decker actinide porphyrins and phthalocyanines. Synthesis and spectroscopic characterization of neutral, oxidized, and reduced homo- and heteroleptic complexes
T2 - Journal of the American Chemical Society
AU - Kadish, Karl M.
AU - Moninot, G
AU - Hu, Y.
AU - Dubois, D.
AU - Ibnlfassi, A
AU - Barbe, J. M.
AU - Guilard, Roger
PY - 1993
DA - 1993/09/01
PB - American Chemical Society (ACS)
SP - 8153-8166
IS - 18
VL - 115
SN - 0002-7863
SN - 1520-5126
ER -
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@article{1993_Kadish,
author = {Karl M. Kadish and G Moninot and Y. Hu and D. Dubois and A Ibnlfassi and J. M. Barbe and Roger Guilard},
title = {Double-decker actinide porphyrins and phthalocyanines. Synthesis and spectroscopic characterization of neutral, oxidized, and reduced homo- and heteroleptic complexes},
journal = {Journal of the American Chemical Society},
year = {1993},
volume = {115},
publisher = {American Chemical Society (ACS)},
month = {sep},
url = {https://doi.org/10.1021/ja00071a028},
number = {18},
pages = {8153--8166},
doi = {10.1021/ja00071a028}
}
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MLA
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Kadish, Karl M., et al. “Double-decker actinide porphyrins and phthalocyanines. Synthesis and spectroscopic characterization of neutral, oxidized, and reduced homo- and heteroleptic complexes.” Journal of the American Chemical Society, vol. 115, no. 18, Sep. 1993, pp. 8153-8166. https://doi.org/10.1021/ja00071a028.