Host-Guest Chemistry of a New Class of Macrocyclic Multidentate Lewis Acids Comprised of Carborane-Supported Electrophilic Mercury Centers
2
Chemistry and Biochemistry
Publication type: Journal Article
Publication date: 1994-08-01
scimago Q1
wos Q1
SJR: 5.554
CiteScore: 22.5
Impact factor: 15.6
ISSN: 00027863, 15205126
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Abstract
The synthesis and characterization of a family of carborane-supported macrocycles containing electrophilic mercury centers is described. These compounds are multidentate Lewis acids which have been demonstrated to bind anions such as C1-, Br, I-, and closo-BloHlo2- as well as uncharged nucleophilic species. The lithium salts of the anionic complexes (( 1,2-C2BloH10Hg)&)Li,(l.XnLi,; X = C1, Br, n = 1; X = I, n = 1 or 2) were synthesized from the reaction of closo-1,2-Li~-l,2-C~B~~H~~ with HgX2 (X = C1, Br, and I) in 70-80% yields. The free host ( 12lmercuracarborand-4 (1) was obtained by the removal of halide ions from 1.1~~- with AgOAc. The molecular structures of l-CILi, (l.Br)z- (benzo( 15)crown-5)3-Liz(H20)2, and l*Iz(AsPh4)2 have been determined from single-crystal X-ray diffraction studies. 1.ClLi crystallizes in the tetragonal space group P4/mcc, a = 14.3233(8) A, c = 11.2641(7) A, V = 2311 A3, z = 2 (l/! of the tetramer per asymmetricunit), R = 0.041, R, = 0.060. (l.Br)z(dibenzo( 1 5)crown-5)yLi2(H20)2 crystallizes
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Yang X. et al. Host-Guest Chemistry of a New Class of Macrocyclic Multidentate Lewis Acids Comprised of Carborane-Supported Electrophilic Mercury Centers // Journal of the American Chemical Society. 1994. Vol. 116. No. 16. pp. 7142-7159.
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Yang X., Knobler C. B., Zheng Z., Hawthorne M. F. Host-Guest Chemistry of a New Class of Macrocyclic Multidentate Lewis Acids Comprised of Carborane-Supported Electrophilic Mercury Centers // Journal of the American Chemical Society. 1994. Vol. 116. No. 16. pp. 7142-7159.
Cite this
RIS
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TY - JOUR
DO - 10.1021/ja00095a018
UR - https://doi.org/10.1021/ja00095a018
TI - Host-Guest Chemistry of a New Class of Macrocyclic Multidentate Lewis Acids Comprised of Carborane-Supported Electrophilic Mercury Centers
T2 - Journal of the American Chemical Society
AU - Yang, Xiaoguang
AU - Knobler, Carolyn B.
AU - Zheng, Zhiping
AU - Hawthorne, M Frederick
PY - 1994
DA - 1994/08/01
PB - American Chemical Society (ACS)
SP - 7142-7159
IS - 16
VL - 116
SN - 0002-7863
SN - 1520-5126
ER -
Cite this
BibTex (up to 50 authors)
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@article{1994_Yang,
author = {Xiaoguang Yang and Carolyn B. Knobler and Zhiping Zheng and M Frederick Hawthorne},
title = {Host-Guest Chemistry of a New Class of Macrocyclic Multidentate Lewis Acids Comprised of Carborane-Supported Electrophilic Mercury Centers},
journal = {Journal of the American Chemical Society},
year = {1994},
volume = {116},
publisher = {American Chemical Society (ACS)},
month = {aug},
url = {https://doi.org/10.1021/ja00095a018},
number = {16},
pages = {7142--7159},
doi = {10.1021/ja00095a018}
}
Cite this
MLA
Copy
Yang, Xiaoguang, et al. “Host-Guest Chemistry of a New Class of Macrocyclic Multidentate Lewis Acids Comprised of Carborane-Supported Electrophilic Mercury Centers.” Journal of the American Chemical Society, vol. 116, no. 16, Aug. 1994, pp. 7142-7159. https://doi.org/10.1021/ja00095a018.