A highly enantioselective synthesis of phosphate triesters
Тип публикации: Journal Article
Дата публикации: 1990-09-01
scimago Q1
wos Q1
БС1
SJR: 5.489
CiteScore: 24.4
Impact factor: 15.6
ISSN: 00027863, 15205126
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Краткое описание
A general methodology for the preparation of both enantiomers of a variety of trialkyl phosphates with enantiomeric excesses ranging from 87 to 92% is described. Bis(2,4-dichlorophenyl) phosphoramidates bearing a 2-substituted pyrrolidine moiety as the chiral auxiliary are prepared and examined for their stereoselectivity. Considerations based on both the absolute configuration of the product phosphates as well as the X-ray structural determination of one of the bis(2,4-dichlorophenyl) phosphoramidates suggest these substitutions occur with preponderant inversion of configuration at phosphorus
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ГОСТ
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Nakayama K., Thompson W. J. A highly enantioselective synthesis of phosphate triesters // Journal of the American Chemical Society. 1990. Vol. 112. No. 19. pp. 6936-6942.
ГОСТ со всеми авторами (до 50)
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Nakayama K., Thompson W. J. A highly enantioselective synthesis of phosphate triesters // Journal of the American Chemical Society. 1990. Vol. 112. No. 19. pp. 6936-6942.
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TY - JOUR
DO - 10.1021/ja00175a030
UR - https://doi.org/10.1021/ja00175a030
TI - A highly enantioselective synthesis of phosphate triesters
T2 - Journal of the American Chemical Society
AU - Nakayama, Kensaku
AU - Thompson, Wayne J.
PY - 1990
DA - 1990/09/01
PB - American Chemical Society (ACS)
SP - 6936-6942
IS - 19
VL - 112
SN - 0002-7863
SN - 1520-5126
ER -
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@article{1990_Nakayama,
author = {Kensaku Nakayama and Wayne J. Thompson},
title = {A highly enantioselective synthesis of phosphate triesters},
journal = {Journal of the American Chemical Society},
year = {1990},
volume = {112},
publisher = {American Chemical Society (ACS)},
month = {sep},
url = {https://doi.org/10.1021/ja00175a030},
number = {19},
pages = {6936--6942},
doi = {10.1021/ja00175a030}
}
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MLA
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Nakayama, Kensaku, and Wayne J. Thompson. “A highly enantioselective synthesis of phosphate triesters.” Journal of the American Chemical Society, vol. 112, no. 19, Sep. 1990, pp. 6936-6942. https://doi.org/10.1021/ja00175a030.