Journal of the American Chemical Society, volume 110, issue 10, pages 3046-3050
Surface derivatization and isolation of semiconductor cluster molecules
Publication type: Journal Article
Publication date: 1988-05-01
Q1
Q1
SJR: 5.489
CiteScore: 24.4
Impact factor: 14.4
ISSN: 00027863, 15205126
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Abstract
Author(s): Steigerwald, ML; Alivisatos, AP; Gibson, JM; Harris, TD; Kortan, R; Muller, AJ; Thayer, AM; Duncan, TM; Douglass, DC; Brus, LE | Abstract: We describe a synthesis of nanometer-sized clusters of CdSe using organometallic reagents in inverse micellar solution and chemical modification of the surface of these cluster compounds. In particular we show how the clusters grow in the presence of added reagents and how the surface may be terminated and passivated by the addition of organoselenides. Passivation of the surface allows for the removal of the cluster molecules from the reaction medium and the isolation of organometallic molecules which are zinc blende CdSe clusters terminated by covalently attached organic ligands. Preliminary cluster characterization via resonance Raman, infrared, and NMR spectroscopy, X-ray diffraction, transmission electron microscopy, and size-exclusion chromatography is reported. © 1988, American Chemical Society. All rights reserved.
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GOST
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Steigerwald M. L. et al. Surface derivatization and isolation of semiconductor cluster molecules // Journal of the American Chemical Society. 1988. Vol. 110. No. 10. pp. 3046-3050.
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Steigerwald M. L., ALIVISATOS A. P., Gibson J. M., Harris T., Kortan R., Muller A. J., Thayer A. M., Duncan T. K., Douglass D., Brus L. Surface derivatization and isolation of semiconductor cluster molecules // Journal of the American Chemical Society. 1988. Vol. 110. No. 10. pp. 3046-3050.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/ja00218a008
UR - https://doi.org/10.1021/ja00218a008
TI - Surface derivatization and isolation of semiconductor cluster molecules
T2 - Journal of the American Chemical Society
AU - Steigerwald, M L
AU - ALIVISATOS, A. P.
AU - Gibson, J. M.
AU - Harris, Timothy
AU - Kortan, R
AU - Muller, A. J.
AU - Thayer, A. M.
AU - Duncan, Thomas K.
AU - Douglass, D.C.
AU - Brus, Louis
PY - 1988
DA - 1988/05/01
PB - American Chemical Society (ACS)
SP - 3046-3050
IS - 10
VL - 110
SN - 0002-7863
SN - 1520-5126
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{1988_Steigerwald,
author = {M L Steigerwald and A. P. ALIVISATOS and J. M. Gibson and Timothy Harris and R Kortan and A. J. Muller and A. M. Thayer and Thomas K. Duncan and D.C. Douglass and Louis Brus},
title = {Surface derivatization and isolation of semiconductor cluster molecules},
journal = {Journal of the American Chemical Society},
year = {1988},
volume = {110},
publisher = {American Chemical Society (ACS)},
month = {may},
url = {https://doi.org/10.1021/ja00218a008},
number = {10},
pages = {3046--3050},
doi = {10.1021/ja00218a008}
}
Cite this
MLA
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Steigerwald, M. L., et al. “Surface derivatization and isolation of semiconductor cluster molecules.” Journal of the American Chemical Society, vol. 110, no. 10, May. 1988, pp. 3046-3050. https://doi.org/10.1021/ja00218a008.