Diastereotopically distinct secondary deuterium kinetic isotope effects on the thermal isomerization of cyclobutene to butadiene
Тип публикации: Journal Article
Дата публикации: 1988-12-01
SCImago Q1
Tоп 10% SCImago
WOS Q1
БС1
SJR: 5.491
CiteScore: 22
Impact factor: 16.6
ISSN: 00027863, 15205126
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Краткое описание
In order to study the diastereotopically secondary deuterium isotope effects on the thermal isomerization of cyclobutane, the compounds cyclobutene, (1-{sup 2}H)cyclobutene, and (3-{sup 2}H)cyclobutene were prepared, and their gas-phases isomerizations were followed. From the data, correlations between hybridization changes and secondary hydrogen/deuterium isotope effects and the observed diastereotopically distinct hydrogen/deuterium effects suggest that two cyclobutene C3-H bonds may have substantially different hybridizations at the transition state. 16 refs.
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16
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ГОСТ
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Baldwin J. E. et al. Diastereotopically distinct secondary deuterium kinetic isotope effects on the thermal isomerization of cyclobutene to butadiene // Journal of the American Chemical Society. 1988. Vol. 110. No. 25. pp. 8555-8556.
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Baldwin J. E., Reddy V. P., Schaad L., Hess B. Diastereotopically distinct secondary deuterium kinetic isotope effects on the thermal isomerization of cyclobutene to butadiene // Journal of the American Chemical Society. 1988. Vol. 110. No. 25. pp. 8555-8556.
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RIS
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TY - JOUR
DO - 10.1021/ja00233a048
UR - https://doi.org/10.1021/ja00233a048
TI - Diastereotopically distinct secondary deuterium kinetic isotope effects on the thermal isomerization of cyclobutene to butadiene
T2 - Journal of the American Chemical Society
AU - Baldwin, John E.
AU - Reddy, V. Prakash
AU - Schaad, L.J.
AU - Hess, B.A.
PY - 1988
DA - 1988/12/01
PB - American Chemical Society (ACS)
SP - 8555-8556
IS - 25
VL - 110
SN - 0002-7863
SN - 1520-5126
ER -
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BibTex (до 50 авторов)
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@article{1988_Baldwin,
author = {John E. Baldwin and V. Prakash Reddy and L.J. Schaad and B.A. Hess},
title = {Diastereotopically distinct secondary deuterium kinetic isotope effects on the thermal isomerization of cyclobutene to butadiene},
journal = {Journal of the American Chemical Society},
year = {1988},
volume = {110},
publisher = {American Chemical Society (ACS)},
month = {dec},
url = {https://doi.org/10.1021/ja00233a048},
number = {25},
pages = {8555--8556},
doi = {10.1021/ja00233a048}
}
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MLA
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Baldwin, John E., et al. “Diastereotopically distinct secondary deuterium kinetic isotope effects on the thermal isomerization of cyclobutene to butadiene.” Journal of the American Chemical Society, vol. 110, no. 25, Dec. 1988, pp. 8555-8556. https://doi.org/10.1021/ja00233a048.
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