Rates and mechanisms of reactions of nitrogen dioxide with alkenes in solution
Тип публикации: Journal Article
Дата публикации: 1987-11-01
SCImago Q1
Tоп 10% SCImago
WOS Q1
БС1
SJR: 5.491
CiteScore: 22
Impact factor: 16.6
ISSN: 00027863, 15205126
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Краткое описание
Rates of reaction of alkenes with nitrogen dioxide have been determined in aprotic solvents. The reactions are first order in the alkene. At high concentrations of NO/sub 2/N/sub 2/O/sub 4/, a kinetic dependence that is first order in N/sub 2/O/sub 4/ or second order in NO/sub 2/ is observed. As the concentration of NO/sub 2//N/sub 2/O/sub 4/ approaches zero, the kinetic order in NO/sub 2/ approaches unity. These data indicate the presence of at least two distinct reaction pathways: one involving the diamagnetic dimer, N/sub 2/O/sub 4/, in an addition mechanism and the other(s) involving the paramagnetic monomer NO/sub 2/. The reaction of the monomer proceeds, at least in part, through abstraction of allylic hydrogen atoms.
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ГОСТ
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Giamalva D. H. et al. Rates and mechanisms of reactions of nitrogen dioxide with alkenes in solution // Journal of the American Chemical Society. 1987. Vol. 109. No. 23. pp. 7059-7063.
ГОСТ со всеми авторами (до 50)
Скопировать
Giamalva D. H., Kenion G. B., Church D. F., Pryor W. A. Rates and mechanisms of reactions of nitrogen dioxide with alkenes in solution // Journal of the American Chemical Society. 1987. Vol. 109. No. 23. pp. 7059-7063.
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RIS
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TY - JOUR
DO - 10.1021/ja00257a025
UR - https://doi.org/10.1021/ja00257a025
TI - Rates and mechanisms of reactions of nitrogen dioxide with alkenes in solution
T2 - Journal of the American Chemical Society
AU - Giamalva, David H
AU - Kenion, Grant B
AU - Church, Daniel F
AU - Pryor, William A.
PY - 1987
DA - 1987/11/01
PB - American Chemical Society (ACS)
SP - 7059-7063
IS - 23
VL - 109
SN - 0002-7863
SN - 1520-5126
ER -
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BibTex (до 50 авторов)
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@article{1987_Giamalva,
author = {David H Giamalva and Grant B Kenion and Daniel F Church and William A. Pryor},
title = {Rates and mechanisms of reactions of nitrogen dioxide with alkenes in solution},
journal = {Journal of the American Chemical Society},
year = {1987},
volume = {109},
publisher = {American Chemical Society (ACS)},
month = {nov},
url = {https://doi.org/10.1021/ja00257a025},
number = {23},
pages = {7059--7063},
doi = {10.1021/ja00257a025}
}
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MLA
Скопировать
Giamalva, David H., et al. “Rates and mechanisms of reactions of nitrogen dioxide with alkenes in solution.” Journal of the American Chemical Society, vol. 109, no. 23, Nov. 1987, pp. 7059-7063. https://doi.org/10.1021/ja00257a025.
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