Environmental effects on vibronic band intensities in pyrene monomer fluorescence and their application in studies of micellar systems
Тип публикации: Journal Article
Дата публикации: 1977-03-01
scimago Q1
wos Q1
БС1
SJR: 5.489
CiteScore: 24.4
Impact factor: 15.6
ISSN: 00027863, 15205126
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Краткое описание
The fluorescence intensities for various vibronic fine structures in the pyrene monomer fluorescence show strong solvent dependence. In the presence of polar solvents, there is a significant enhancement in the intensity of the 0--0 vibronic band at the expense of other bands. This strong perturbation in the vibronic band intensities is more dependent on the solvent dipole moment than on the bulk solvent dielectric constant. This suggests the operation of some specific solute--solvent dipole--dipole interaction mechanism. The strong perturbation of the vibronic band intensities has been used as a probe to accurately determine critical micelle concentrations and also to investigate the extent of water penetration in micellar systems.
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Kalyanasundaram K., Thomas J. K. Environmental effects on vibronic band intensities in pyrene monomer fluorescence and their application in studies of micellar systems // Journal of the American Chemical Society. 1977. Vol. 99. No. 7. pp. 2039-2044.
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Kalyanasundaram K., Thomas J. K. Environmental effects on vibronic band intensities in pyrene monomer fluorescence and their application in studies of micellar systems // Journal of the American Chemical Society. 1977. Vol. 99. No. 7. pp. 2039-2044.
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TY - JOUR
DO - 10.1021/ja00449a004
UR - https://doi.org/10.1021/ja00449a004
TI - Environmental effects on vibronic band intensities in pyrene monomer fluorescence and their application in studies of micellar systems
T2 - Journal of the American Chemical Society
AU - Kalyanasundaram, K.
AU - Thomas, J K
PY - 1977
DA - 1977/03/01
PB - American Chemical Society (ACS)
SP - 2039-2044
IS - 7
VL - 99
SN - 0002-7863
SN - 1520-5126
ER -
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BibTex (до 50 авторов)
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@article{1977_Kalyanasundaram,
author = {K. Kalyanasundaram and J K Thomas},
title = {Environmental effects on vibronic band intensities in pyrene monomer fluorescence and their application in studies of micellar systems},
journal = {Journal of the American Chemical Society},
year = {1977},
volume = {99},
publisher = {American Chemical Society (ACS)},
month = {mar},
url = {https://doi.org/10.1021/ja00449a004},
number = {7},
pages = {2039--2044},
doi = {10.1021/ja00449a004}
}
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MLA
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Kalyanasundaram, K., and J K Thomas. “Environmental effects on vibronic band intensities in pyrene monomer fluorescence and their application in studies of micellar systems.” Journal of the American Chemical Society, vol. 99, no. 7, Mar. 1977, pp. 2039-2044. https://doi.org/10.1021/ja00449a004.