Isotopic perturbation of resonance. Carbon-13 nuclear magnetic resonance of 2-deuterio-2-bicyclo[2.1.1]hexyl cation
Тип публикации: Journal Article
Дата публикации: 1977-11-01
SCImago Q1
Tоп 10% SCImago
WOS Q1
БС1
SJR: 5.491
CiteScore: 22
Impact factor: 16.6
ISSN: 00027863, 15205126
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Краткое описание
The /sup 13/C NMR spectra bicylo(2.1.1) hexyl cation and its derivatives substituted with deuterium on the methine and methylene positions were observed. The small relative splitting of the methine carbon peak is evidence that isotopic perturbation of resonance is being observed and not an equilibrium isotope effect. This, in turn, is evidence that the structure is sigma-delocalized and probably symmetrically bridged. (JSR)
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ГОСТ
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Saunders M. et al. Isotopic perturbation of resonance. Carbon-13 nuclear magnetic resonance of 2-deuterio-2-bicyclo[2.1.1]hexyl cation // Journal of the American Chemical Society. 1977. Vol. 99. No. 24. pp. 8072-8073.
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Saunders M., Kates M. R., Wiberg K. B., Pratt W. B. Isotopic perturbation of resonance. Carbon-13 nuclear magnetic resonance of 2-deuterio-2-bicyclo[2.1.1]hexyl cation // Journal of the American Chemical Society. 1977. Vol. 99. No. 24. pp. 8072-8073.
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TY - JOUR
DO - 10.1021/ja00466a062
UR - https://doi.org/10.1021/ja00466a062
TI - Isotopic perturbation of resonance. Carbon-13 nuclear magnetic resonance of 2-deuterio-2-bicyclo[2.1.1]hexyl cation
T2 - Journal of the American Chemical Society
AU - Saunders, Martin
AU - Kates, Mandes R
AU - Wiberg, Kenneth B.
AU - Pratt, W B
PY - 1977
DA - 1977/11/01
PB - American Chemical Society (ACS)
SP - 8072-8073
IS - 24
VL - 99
SN - 0002-7863
SN - 1520-5126
ER -
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BibTex (до 50 авторов)
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@article{1977_Saunders,
author = {Martin Saunders and Mandes R Kates and Kenneth B. Wiberg and W B Pratt},
title = {Isotopic perturbation of resonance. Carbon-13 nuclear magnetic resonance of 2-deuterio-2-bicyclo[2.1.1]hexyl cation},
journal = {Journal of the American Chemical Society},
year = {1977},
volume = {99},
publisher = {American Chemical Society (ACS)},
month = {nov},
url = {https://doi.org/10.1021/ja00466a062},
number = {24},
pages = {8072--8073},
doi = {10.1021/ja00466a062}
}
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MLA
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Saunders, Martin, et al. “Isotopic perturbation of resonance. Carbon-13 nuclear magnetic resonance of 2-deuterio-2-bicyclo[2.1.1]hexyl cation.” Journal of the American Chemical Society, vol. 99, no. 24, Nov. 1977, pp. 8072-8073. https://doi.org/10.1021/ja00466a062.
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